{"id":"W4412644204","doi":"10.1002/anie.202512411","title":"Chloromethoxytrityls: Tuning the SOMO Level of Stable Luminescent Radicals","year":2025,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Fonds de recherche du Québec – Nature et technologies; Natural Sciences and Engineering Research Council of Canada; McGill University","keywords":"Radical; Chemistry; Photochemistry; Density functional theory; Luminescence; Excited state; Open shell; Molecular orbital; Computational chemistry; Molecule; Materials science; Atomic physics; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001755173,0.0002013253,0.0001245305,0.0001556699,0.0001337235,0.0002843183,0.0003361927,0.000285254,0.001580991],"category_scores_gemma":[0.0002883559,0.0001025554,0.0001144626,0.0001403882,0.0001785562,0.0003327451,0.0003228705,0.0004432305,0.0002454327],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000224636,"about_ca_system_score_gemma":0.0001175584,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002810291,"about_ca_topic_score_gemma":0.0004792154,"domain_scores_codex":[0.9999,0.00001352877,0.00000730063,0.00002693027,0.00003019446,0.00002211276],"domain_scores_gemma":[0.9998698,0.00003857643,0.0000446436,0.00001346444,0.0000204871,0.00001293412],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001212545,0.00002433224,0.0002443205,0.0001366605,0.000007795072,0.00005028629,0.00003956041,0.0005577947,0.9934341,0.0005035184,0.0001301751,0.004750171],"study_design_scores_gemma":[0.00002861893,0.0002599399,0.0004075322,0.000009573306,0.0000103283,0.00005520722,0.00001576927,0.002235022,0.9951556,0.0001044135,0.001710742,0.000007278022],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9935522,0.001150978,0.003393893,0.00009972713,0.00001736604,0.00001570107,0.0001005538,0.00008282111,0.001586668],"genre_scores_gemma":[0.9951819,0.00052971,0.003351202,0.00004085386,0.000006605808,0.0000215581,0.00009404478,0.00003441956,0.0007396846],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001580991,"threshold_uncertainty_score":0.005288899,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04240540640238817,"score_gpt":0.2985684330930401,"score_spread":0.2561630266906519,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}