{"id":"W4412855908","doi":"10.1016/j.jcis.2025.138514","title":"Efficient electrosynthesis of ammonia from nitrate reduction over the perylene-3,4,9,10-tetracarboxylic diimide-based heterostructure","year":2025,"lang":"en","type":"article","venue":"Journal of Colloid and Interface Science","topic":"Ammonia Synthesis and Nitrogen Reduction","field":"Chemical Engineering","cited_by":0,"is_retracted":false,"has_abstract":false,"ca_institutions":"Ministry of Education and Child Care","funders":"Ministry of Science and Technology of the People's Republic of China; National Natural Science Foundation of China","keywords":"Diimide; Electrochemistry; Chemistry; Reversible hydrogen electrode; Electrosynthesis; Heterojunction; Perylene; Electrode; Chemical engineering; Photochemistry; Materials science; Working electrode; Organic chemistry; Molecule; Optoelectronics; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000490285,0.000142125,0.0002609975,0.000201973,0.0001625502,0.00007740663,0.0003285017,0.00006582018,0.00005572678],"category_scores_gemma":[0.0002433928,0.00009150947,0.0001227595,0.0005737129,0.0003793297,0.0001272402,0.00004208522,0.0002592998,8.986989e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001282846,"about_ca_system_score_gemma":0.0001851215,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003752084,"about_ca_topic_score_gemma":0.000001866161,"domain_scores_codex":[0.9987285,0.00003290076,0.000439925,0.0001972087,0.0003908107,0.0002106804],"domain_scores_gemma":[0.9990703,0.0001320565,0.0003161394,0.0001871698,0.0002235047,0.00007078581],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001524836,0.00003641656,0.0001373036,0.00001204979,0.00003159075,1.546727e-7,0.0001183932,0.01211194,0.9863064,0.00005635897,0.00005698462,0.0009799071],"study_design_scores_gemma":[0.0002363922,0.00008682662,0.003438219,0.0001702137,0.00005890162,0.00001603205,0.0002277362,0.03317119,0.9623225,0.00008302894,0.0001068966,0.00008201335],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995995,0.001255708,0.001848891,0.0002996953,0.0004119833,0.00007976069,0.000006267834,0.000009632425,0.00009309409],"genre_scores_gemma":[0.9991431,0.00003703729,0.0006077792,0.00001936418,0.00007407845,0.00000196633,1.34604e-7,0.000007528633,0.0001090505],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02398386,"threshold_uncertainty_score":0.3731648,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00475993723509783,"score_gpt":0.2357471710504711,"score_spread":0.2309872338153733,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}