{"id":"W4413048784","doi":"10.1002/adma.202511662","title":"Dynamic Confinement and High‐Entropy Catalytic Synergy Engineering in Hollow Nano‐Metal‐Organic Frameworks","year":2025,"lang":"en","type":"article","venue":"Advanced Materials","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Light Source (Canada); University of Saskatchewan","funders":"National Natural Science Foundation of China","keywords":"Materials science; Nano-; Nanotechnology; Catalysis; Metal-organic framework; Metal; Entropy (arrow of time); Thermodynamics; Physical chemistry; Metallurgy; Adsorption; Composite material; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000166819,0.0002654525,0.0004758147,0.00009879839,0.000066239,0.00007948281,0.0002275258,0.0002995963,0.001869685],"category_scores_gemma":[0.0003134659,0.0002662306,0.00003979577,0.0002318435,0.00004272024,0.00008642163,0.0001285919,0.000221557,0.00002691571],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001339883,"about_ca_system_score_gemma":0.00004047419,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003775755,"about_ca_topic_score_gemma":0.00001943312,"domain_scores_codex":[0.9985284,0.00001538202,0.00050955,0.0004512612,0.0001484005,0.0003470475],"domain_scores_gemma":[0.9990522,0.0001760497,0.0001266045,0.000540845,0.00003837518,0.00006593294],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001630806,0.00005409048,0.00001615406,0.0001827753,0.00005019407,0.000004113587,0.00002098321,0.0001649344,0.9872493,0.009456561,0.0000275925,0.00275699],"study_design_scores_gemma":[0.0006425068,0.00000846446,0.0003763178,0.000420926,0.00005705555,0.000003305967,0.00005263675,0.0002512024,0.9926571,0.002084038,0.003179508,0.0002669891],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9939825,0.0007585093,0.00377366,0.0004694948,0.0003024256,0.0001914535,0.00004363503,0.0001197712,0.0003585537],"genre_scores_gemma":[0.9944965,0.0004290217,0.003637925,0.0001301646,0.00003328278,0.0001882596,0.00006158595,0.00004113323,0.0009820911],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007372523,"threshold_uncertainty_score":0.999979,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003329329294769187,"score_gpt":0.216124125549874,"score_spread":0.2127947962551048,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}