{"id":"W4413102074","doi":"10.1021/acsomega.5c04003","title":"Confirmation of Microwave-Assisted Synthesis of Chloro-Boron Subphthalocyanines and Chloro-Boron Subnaphthalocyanines with Rapid Screening and Data Acquisition via HPLC-PDA","year":2025,"lang":"en","type":"article","venue":"ACS Omega","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick; University of Toronto","funders":"Hatch; Natural Sciences and Engineering Research Council of Canada; Government of Ontario","keywords":"Boron; Microwave; High-performance liquid chromatography; Chromatography; Chemistry; Materials science; Organic chemistry; Computer science; Telecommunications","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004030375,0.0005053682,0.0001729462,0.0003604766,0.0001808425,0.0001871207,0.0002405378,0.0002553738,0.001511576],"category_scores_gemma":[0.0004640029,0.0001494503,0.0002253873,0.000272381,0.0001890412,0.000254107,0.0002057469,0.0004111197,0.0005315895],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001604466,"about_ca_system_score_gemma":0.0002201193,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004384623,"about_ca_topic_score_gemma":0.000992773,"domain_scores_codex":[0.9997256,0.00004830623,0.00002478688,0.00006146737,0.0001054458,0.00003429504],"domain_scores_gemma":[0.9997309,0.0000579176,0.00006980549,0.00003948997,0.00007609809,0.00002572766],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002712616,0.00001517452,0.0001104533,0.00003681271,0.00000361559,0.00003791526,0.00002071047,0.00005123036,0.9980248,0.00005681727,0.00003275808,0.001582637],"study_design_scores_gemma":[0.00000249402,0.0001283259,0.0005386395,0.000001849796,0.000004325886,0.00007281105,0.000009602936,0.0003693613,0.9982663,0.00001476273,0.0005881794,0.000003400184],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9388793,0.00129338,0.05223786,0.0001559558,0.00004029259,0.0002847743,0.001283409,0.0005089958,0.005316094],"genre_scores_gemma":[0.9440791,0.001047035,0.04959744,0.00005481111,0.00001701714,0.0001900389,0.0009374269,0.00008204154,0.003995202],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001511576,"threshold_uncertainty_score":0.005056739,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01871635621499929,"score_gpt":0.2609530256669101,"score_spread":0.2422366694519109,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}