{"id":"W4413110330","doi":"10.1021/acs.jpcb.5c03367","title":"Photobasicity-Triggered Twisted Intramolecular Charge Transfer of Push–Pull Chromophores","year":2025,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph; University of Lethbridge","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Alberta Innovates; Government of Ontario; University of Lethbridge","keywords":"Protonation; Chromophore; Intramolecular force; Photochemistry; Fluorescence; Chemistry; Acceptor; Excited state; Solvent; Proton; Absorption (acoustics); Materials science; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002434492,0.0003203579,0.0006868004,0.00002542742,0.0001189156,0.0000181308,0.0007994382,0.0001358356,0.0003260453],"category_scores_gemma":[0.00009929566,0.0002284679,0.000489078,0.0003151525,0.0003646297,0.0000663488,0.00005022818,0.000804803,0.000002646165],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008479584,"about_ca_system_score_gemma":0.0001781862,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001604199,"about_ca_topic_score_gemma":6.767403e-7,"domain_scores_codex":[0.9983004,0.00003618041,0.0006441719,0.00019343,0.0004447307,0.000381052],"domain_scores_gemma":[0.998775,0.0002513655,0.0001723248,0.0004241976,0.0002701458,0.0001069727],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006036994,0.0005153024,0.00002112509,0.0008348109,0.0005885795,0.00001538443,0.0004757723,0.0000193953,0.9960288,0.00007057897,0.000461228,0.0003653649],"study_design_scores_gemma":[0.001207376,0.00005756812,0.0000229554,0.0003017892,0.0004149259,0.00004088048,0.0001869742,0.00009791103,0.9952114,0.0007160571,0.001550243,0.0001919358],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9824807,0.001070053,0.0002036423,0.0003157089,0.00003086738,0.00006783773,0.00004210966,0.00002297188,0.01576611],"genre_scores_gemma":[0.9988548,0.000169964,0.000007725142,0.00005739902,0.0002782698,0.000008297152,0.000007568516,0.00001987387,0.0005960835],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01637412,"threshold_uncertainty_score":0.9316652,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00611579049391755,"score_gpt":0.2331202501501561,"score_spread":0.2270044596562385,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}