{"id":"W4413408705","doi":"10.1016/b978-0-323-96025-0.00145-9","title":"Higher Order Cycloadditions","year":2025,"lang":"en","type":"book-chapter","venue":"Elsevier eBooks","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":false,"ca_institutions":"Queen's University","funders":"","keywords":"Order (exchange); Computer science; Mathematics; Business","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.00004601908,0.0006050929,0.0005599093,0.0001774375,0.0001850927,0.00006313475,0.0003802922,0.0007982244,0.03711612],"category_scores_gemma":[0.00001748469,0.0006349064,0.0003570135,0.00001970737,0.0001090496,0.00003556865,0.0001975409,0.0009707503,0.001548419],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003147406,"about_ca_system_score_gemma":0.0002888197,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":8.681659e-7,"about_ca_topic_score_gemma":0.00001286268,"domain_scores_codex":[0.9980286,0.000007507953,0.0004972581,0.0006928804,0.0004226305,0.0003510958],"domain_scores_gemma":[0.9981982,0.00007849342,0.0002675188,0.001058988,0.0002465794,0.0001502583],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.000009089104,0.0000101232,2.617632e-7,0.0003474827,0.0001770451,0.00004824357,0.00003953031,2.650282e-7,0.00141856,0.04132911,0.003580461,0.9530398],"study_design_scores_gemma":[0.0002874228,0.00000842999,5.346852e-7,0.0006811763,0.0002656119,0.00001901154,0.00001197772,8.413263e-7,0.002405538,0.01619316,0.9795413,0.0005850223],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.000003069503,0.0008157972,0.000007255735,0.00009424701,0.0007761287,0.0002068627,0.0003722889,0.0004136711,0.9973107],"genre_scores_gemma":[0.00005695022,0.0001253882,0.0007165883,0.0003286026,0.000881804,0.0001164219,0.0004714162,0.0001507941,0.997152],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.9759608,"threshold_uncertainty_score":0.9996102,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01233736572870668,"score_gpt":0.2329912094001752,"score_spread":0.2206538436714685,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}