{"id":"W4413745816","doi":"10.1021/acs.orglett.5c00342","title":"Cooperative Copper/Eosin Y-Catalyzed Photochemical Oxidative Coupling Reactions of Indolines for the Synthesis of 1,5′-Biindoles","year":2025,"lang":"en","type":"article","venue":"Organic Letters","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"IONICS Mass Spectrometry (Canada)","funders":"Key Research and Development Program of Zhejiang Province; National Key Research and Development Program of China; Natural Science Foundation of Zhejiang Province; Ningbo Municipal Bureau of Science and Technology; China Postdoctoral Science Foundation; National Natural Science Foundation of China","keywords":"Chemistry; Eosin Y; Oxidative coupling of methane; Catalysis; Eosin; Copper; Oxidative phosphorylation; Photochemistry; Coupling (piping); Combinatorial chemistry; Organic chemistry; Staining; Biochemistry; Photocatalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003035271,0.0001584132,0.0003168213,0.00007829183,0.0001243137,0.00001609136,0.0002590688,0.00009535594,0.000486699],"category_scores_gemma":[0.002753595,0.0001280026,0.0001294804,0.0004131935,0.0002751639,0.00006361785,0.00007079911,0.0001415269,0.000002914007],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001131211,"about_ca_system_score_gemma":0.000178167,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004447857,"about_ca_topic_score_gemma":0.00000744383,"domain_scores_codex":[0.9989173,0.0000213872,0.0004804001,0.0002517624,0.0001818362,0.0001472805],"domain_scores_gemma":[0.9952517,0.003795271,0.0002636736,0.0003810389,0.0002809562,0.00002742745],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001230177,0.00006762402,0.0004353318,0.0001895988,0.0002946196,2.016452e-7,0.0001656168,0.000323095,0.9942964,0.0004756247,0.003493341,0.0001355376],"study_design_scores_gemma":[0.00057592,0.000003440493,0.00009305182,0.0001622678,0.0002174007,0.000002693288,0.0007184957,0.001608953,0.9955562,0.00004026058,0.0009131471,0.0001081152],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8935094,0.0001598442,0.09968446,0.005254516,0.0002378474,0.0004720747,0.0002700021,0.00006176984,0.0003500415],"genre_scores_gemma":[0.9966778,0.00002844625,0.002300187,0.0003390489,0.0001041739,0.0001681874,0.0000902498,0.00002850366,0.0002634037],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1031684,"threshold_uncertainty_score":0.5329013,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01893638704698194,"score_gpt":0.2851392730452396,"score_spread":0.2662028859982577,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}