{"id":"W4413787717","doi":"10.1021/acsnano.5c08032","title":"Highly Exposed Subnanometric Palladium Ensembles on Yttrium Oxide Enable Boosted Catalytic Performance for Heck Cross-Coupling Reactions","year":2025,"lang":"en","type":"article","venue":"ACS Nano","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Northeast Petroleum University; Natural Science Foundation of Heilongjiang Province; Key Laboratory of Functional Inorganic Materials Chemistry Ministry of Education; National Natural Science Foundation of China","keywords":"Palladium; Catalysis; Yttrium; Materials science; Coupling (piping); Oxide; Heck reaction; Chemical engineering; Nanotechnology; Chemistry; Organic chemistry; Composite material; Metallurgy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005997354,0.0002580955,0.0001468807,0.0001537646,0.00007754144,0.000281349,0.0002921361,0.0001644976,0.0008310878],"category_scores_gemma":[0.0001167262,0.0001714721,0.00009644889,0.0001373714,0.0001374661,0.0002319114,0.0002665495,0.0003799521,0.000292993],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002463498,"about_ca_system_score_gemma":0.0001126745,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004884017,"about_ca_topic_score_gemma":0.001192664,"domain_scores_codex":[0.9999208,0.000004091445,0.000005580499,0.00002435333,0.00002699058,0.00001816145],"domain_scores_gemma":[0.9999732,0.000003983728,0.000007758689,0.000004089688,0.000004571859,0.000006445455],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002553212,0.00001047088,0.000120843,0.0000309383,0.000005167918,0.00003522939,0.00001407582,0.0002074926,0.9963434,0.0002223366,0.0001102121,0.002874136],"study_design_scores_gemma":[0.000003470872,0.00005462653,0.0004888577,0.000001726485,0.000007635726,0.00003816479,0.000009751192,0.001882157,0.9962451,0.00002871027,0.001236524,0.000003307977],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9890677,0.0006531171,0.007017986,0.00005694902,0.00003042708,0.00001115869,0.0001176745,0.0002442478,0.002800782],"genre_scores_gemma":[0.995587,0.0003426706,0.002860259,0.00001272396,0.000005270532,0.000008241273,0.000110043,0.0000274132,0.001046486],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008310878,"threshold_uncertainty_score":0.002780318,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02294183054612934,"score_gpt":0.2832196557644009,"score_spread":0.2602778252182716,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}