{"id":"W4413905421","doi":"10.1039/d5sc04390e","title":"Mechanochemical synthesis of π-conjugated naphthotetrathiophene-based covalent organic frameworks and their post-modification <i>via</i> the Doebner reaction","year":2025,"lang":"en","type":"article","venue":"Chemical Science","topic":"Covalent Organic Framework Applications","field":"Materials Science","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"Concordia University; Institut National de la Recherche Scientifique; McGill University","funders":"Natural Sciences and Engineering Research Council of Canada; University of Birmingham; Fonds de recherche du Québec – Nature et technologies; Leverhulme Trust","keywords":"Conjugated system; Covalent bond; Chemistry; Organic synthesis; Combinatorial chemistry; Organic chemistry; Chemical engineering; Nanotechnology; Materials science; Catalysis; Engineering; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001035298,0.0002030823,0.0002396166,0.000101479,0.0003128557,0.0001017403,0.0009596463,0.0002932327,0.0001514592],"category_scores_gemma":[0.001805355,0.0001368903,0.00006499419,0.00162084,0.001461553,0.0001765741,0.0002319203,0.0004353453,0.00002079494],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001872697,"about_ca_system_score_gemma":0.0003190585,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000272028,"about_ca_topic_score_gemma":0.000002855351,"domain_scores_codex":[0.9980665,0.00005997323,0.0004211731,0.0006751345,0.0004164327,0.0003607612],"domain_scores_gemma":[0.997438,0.001005052,0.0001944255,0.0008622217,0.0003815756,0.0001187524],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003121841,0.0001017529,0.0000330415,0.00003130404,0.000004090255,1.313328e-7,0.0000924999,0.000002554646,0.9952182,0.001620481,0.00005274218,0.002811958],"study_design_scores_gemma":[0.0001201269,0.0000134527,0.0003839907,0.00009598966,0.00003094272,0.000005470488,0.00009986347,0.001648658,0.9926732,0.004609664,0.0001722103,0.0001464665],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9665006,0.0001290368,0.02624514,0.00613892,0.0001920672,0.0004226484,0.0000173668,0.0001148344,0.0002394239],"genre_scores_gemma":[0.9970177,0.00001825615,0.002031192,0.0007533098,0.00003448354,0.0001107863,0.000005156205,0.00001238245,0.00001668011],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03051719,"threshold_uncertainty_score":0.5582224,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007648990240887605,"score_gpt":0.2429751868901751,"score_spread":0.2353261966492875,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}