{"id":"W4413931458","doi":"10.1002/chem.202502113","title":"Host Cavities Enhance the Photocatalytic Conversion of <i>α</i>‐Terpinene to Ascaridole Under Visible‐Light Irradiation","year":2025,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Trinity College","funders":"Office of Science; Heriot-Watt University; Engineering and Physical Sciences Research Council; U.S. Department of Energy","keywords":"Singlet oxygen; Chemistry; BODIPY; Photochemistry; Photocatalysis; Substituent; Host (biology); Substrate (aquarium); Molecule; Oxygen; Stereochemistry; Catalysis; Organic chemistry; Fluorescence","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008623124,0.000237264,0.0001585599,0.00008104867,0.00006101583,0.0002324864,0.000176905,0.0001681461,0.001363855],"category_scores_gemma":[0.0002195124,0.0001061927,0.0001297697,0.00004746995,0.0001631425,0.0001911597,0.0001629286,0.0002303887,0.0003050835],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001437071,"about_ca_system_score_gemma":0.00009017663,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003114526,"about_ca_topic_score_gemma":0.0004166081,"domain_scores_codex":[0.9999431,0.000009917805,0.000002824489,0.00001045302,0.00001557198,0.00001806219],"domain_scores_gemma":[0.9998549,0.00004698155,0.00003965399,0.00001660635,0.00001573515,0.00002604551],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003713361,0.000008144648,0.00003188494,0.0000147269,0.0000012673,0.00002110837,0.000008327414,0.000051737,0.9993277,0.00005692715,0.00001109071,0.000429903],"study_design_scores_gemma":[0.000004070323,0.00005987883,0.0002888045,0.00000142412,0.000002443884,0.00003325545,0.00000423308,0.0003131839,0.9989219,0.000005682103,0.0003639046,0.000001253467],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.997305,0.000231148,0.00107012,0.00001929194,0.000007034675,0.00000991876,0.00003793422,0.00007202208,0.001247528],"genre_scores_gemma":[0.9978458,0.0001431193,0.0008240631,0.000007077975,0.000002653438,0.000005565753,0.00003751039,0.00001006529,0.001124279],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001363855,"threshold_uncertainty_score":0.004562497,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007262059241874181,"score_gpt":0.2329301265854318,"score_spread":0.2256680673435576,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}