{"id":"W4414081585","doi":"10.1021/acs.accounts.5c00513","title":"Quinoline as a Photochemical Toolbox: From Substrate to Catalyst and Beyond","year":2025,"lang":"en","type":"article","venue":"Accounts of Chemical Research","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"Centre in Green Chemistry and Catalysis","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation; National Natural Science Foundation of China; Canada Research Chairs; Fonds Québécois de la Recherche sur la Nature et les Technologies; Chinese University of Hong Kong, Shenzhen","keywords":"Radical; Substrate (aquarium); Quinoline; Catalysis; Hydroamination; Redox; Acceptor; Organic synthesis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005451147,0.0004263796,0.0003084086,0.0003160411,0.0004138048,0.001300315,0.0005941585,0.0007304588,0.002729964],"category_scores_gemma":[0.0004653251,0.0001976607,0.0002354156,0.0002379545,0.001056952,0.00236079,0.001399638,0.001763738,0.001039155],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004553973,"about_ca_system_score_gemma":0.0005256934,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003014929,"about_ca_topic_score_gemma":0.0005142091,"domain_scores_codex":[0.9998149,0.00003581039,0.000009784136,0.00004603182,0.00005149968,0.00004194516],"domain_scores_gemma":[0.9998168,0.00006199595,0.00002171532,0.00003093949,0.00003149088,0.00003707483],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002424512,0.0002218002,0.00103607,0.002598214,0.00004759749,0.00145713,0.001486197,0.002036006,0.453541,0.3240377,0.01308228,0.2002136],"study_design_scores_gemma":[0.00003450271,0.0007526241,0.0008962265,0.0004393118,0.00005640026,0.00152801,0.0005306797,0.003170463,0.3177004,0.0484803,0.6263109,0.0001001179],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"review","genre_gemma":"empirical","genre_scores_codex":[0.2510577,0.4798258,0.1169354,0.01874616,0.002764572,0.0001769082,0.0005930164,0.001565609,0.1283349],"genre_scores_gemma":[0.7686759,0.181312,0.02741733,0.002646263,0.001004918,0.0001682571,0.0003134736,0.0002454314,0.0182163],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.002729964,"threshold_uncertainty_score":0.009132624,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02812462001097651,"score_gpt":0.3744225221874216,"score_spread":0.3462979021764451,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}