{"id":"W4414148503","doi":"10.3847/1538-4365/adf95d","title":"The Synchrotron-based Far-infrared Spectrum of Propargylamine","year":2025,"lang":"en","type":"article","venue":"The Astrophysical Journal Supplement Series","topic":"Molecular Spectroscopy and Structure","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Light Source (Canada)","funders":"","keywords":"Rotational–vibrational spectroscopy; Molecule; Infrared; Spectral line; Infrared spectroscopy; Fourier transform; Hot band; Spectrometer; Fourier transform infrared spectroscopy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001363848,0.0002068563,0.000245638,0.00002571367,0.0006658973,0.0001351977,0.0006693773,0.0000416371,0.0007420727],"category_scores_gemma":[0.00004000633,0.0001067459,0.000222152,0.0001618018,0.0003341673,0.00006951581,0.0001103692,0.000513592,0.000003412106],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007377242,"about_ca_system_score_gemma":0.0001589491,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001173563,"about_ca_topic_score_gemma":0.0000117372,"domain_scores_codex":[0.9985613,0.00007207374,0.0004059091,0.0001533538,0.0004066844,0.0004006432],"domain_scores_gemma":[0.9990854,0.00009757571,0.0002251024,0.0004657918,0.00006645026,0.00005971188],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0009996713,0.0001214877,0.0006051527,0.00007535626,0.0003518056,0.00002413268,0.00009682315,0.0003906575,0.8036331,0.1879694,0.003682116,0.00205029],"study_design_scores_gemma":[0.0008434738,0.0002484517,0.002063009,0.00007210136,0.0001098158,0.00002059175,0.0003700947,0.0003224601,0.9058031,0.06423298,0.02576376,0.0001501348],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8264877,0.001075197,0.1084003,0.05886543,0.0008024027,0.0006105535,0.0002224707,0.0001097297,0.003426182],"genre_scores_gemma":[0.9938683,0.00005395747,0.003220633,0.0001134905,0.000297064,0.0000217925,0.00001628037,0.00001544028,0.002393063],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1673806,"threshold_uncertainty_score":0.8125175,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003006117238960407,"score_gpt":0.2261730516660254,"score_spread":0.223166934427065,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}