{"id":"W4414572973","doi":"10.1016/j.nanoen.2025.111485","title":"A versatile electrocatalytic [3+2] ring expansion approach for efficient electrosynthesis of oxa-/aza-heterocyclic compounds","year":2025,"lang":"en","type":"article","venue":"Nano Energy","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":false,"ca_institutions":"Ministry of Education and Child Care","funders":"Science and Technology Support Program of Jiangsu Province; Government of Jiangsu Province; Natural Science Foundation of Jiangsu Province; National Natural Science Foundation of China","keywords":"Electrosynthesis; Electrochemistry; Acetonitrile; Catalysis; Ring (chemistry); Nanomaterial-based catalyst; Noble metal; Transition metal","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001927741,0.0004383982,0.0001900304,0.0002374351,0.0002183742,0.0002687676,0.0005069313,0.0003470161,0.00250738],"category_scores_gemma":[0.0001163764,0.0001634575,0.0001673204,0.0001625742,0.0002264851,0.0004846518,0.0004674316,0.0007381904,0.0007227572],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002550971,"about_ca_system_score_gemma":0.0001845359,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002372319,"about_ca_topic_score_gemma":0.0007471905,"domain_scores_codex":[0.9998858,0.00001301959,0.00000801884,0.00003206089,0.00002795606,0.00003311839],"domain_scores_gemma":[0.9999652,0.000007589155,0.000008074623,0.000005838251,0.000005101565,0.000008136208],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006585307,0.00006110613,0.00005380966,0.0001111768,0.00001015489,0.0001241378,0.00004976173,0.0001876203,0.9851612,0.002097318,0.0005321506,0.01154577],"study_design_scores_gemma":[0.00001894285,0.0001586318,0.0003025672,0.000006111075,0.000008680157,0.00017709,0.00001243119,0.00112278,0.9915988,0.0002563372,0.006324348,0.00001328654],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8782896,0.005622173,0.0755942,0.00103158,0.000449374,0.000275935,0.0007566178,0.001164802,0.03681575],"genre_scores_gemma":[0.9798281,0.001354773,0.01305913,0.0001882638,0.00005230101,0.00007652391,0.0002138619,0.00006917911,0.005157833],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00250738,"threshold_uncertainty_score":0.008388042,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008110716912655537,"score_gpt":0.2344391216576979,"score_spread":0.2263284047450423,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}