{"id":"W4414846911","doi":"10.1021/jacs.5c12988","title":"Tuning the Degradability Profiles of Polyesters with Indium-Catalyzed Incorporation of Poly(ε-thiocaprolactone) Blocks","year":2025,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Synthesis and properties of polymers","field":"Materials Science","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Division of Chemistry; Natural Sciences and Engineering Research Council of Canada","keywords":"Cationic polymerization; Polymerization; Copolymer; Macromolecule; Polymer; Degradation (telecommunications); Polyester; Hydrolysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007987431,0.0001222382,0.0003996755,0.00001992468,0.00009651956,0.00002261907,0.0006697404,0.00004216314,0.00001739307],"category_scores_gemma":[0.0002003749,0.00005469719,0.000303919,0.0003739599,0.001427501,0.0001076944,0.0001351622,0.0002262786,2.475383e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007594487,"about_ca_system_score_gemma":0.0002742549,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003309301,"about_ca_topic_score_gemma":0.000003073361,"domain_scores_codex":[0.998639,0.0001352874,0.0005292098,0.0001218367,0.0004150315,0.0001595608],"domain_scores_gemma":[0.9976722,0.0002927377,0.001507613,0.0003191092,0.0001673316,0.00004103707],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003078518,0.00006780643,0.01203533,0.00003446854,0.0000776631,1.159162e-7,0.0007908607,0.0000109804,0.9839458,0.00001221138,0.0002392127,0.002477627],"study_design_scores_gemma":[0.0002194693,0.00008192097,0.006529,0.0001244806,0.00009583771,0.000006724918,0.002333081,0.0000567351,0.9903606,0.00009679735,0.00003024072,0.00006518271],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9958718,0.0003535658,0.0002881962,0.003200011,0.00008629528,0.0001126472,0.000007499516,0.000005409205,0.00007452749],"genre_scores_gemma":[0.9966698,0.00001606621,0.002935968,0.0002972615,0.00004430886,0.000002978109,3.463915e-7,0.000007296583,0.00002600046],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006414654,"threshold_uncertainty_score":0.5259685,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01143777343801062,"score_gpt":0.233177439635997,"score_spread":0.2217396661979864,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}