{"id":"W4414948199","doi":"10.1016/j.jorganchem.2025.123891","title":"The halogenation reaction of substituted triosmium clusters","year":2025,"lang":"en","type":"article","venue":"Journal of Organometallic Chemistry","topic":"Vanadium and Halogenation Chemistry","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":false,"ca_institutions":"Simon Fraser University","funders":"National University of Singapore; Nanyang Technological University; Trường Đại học Nha Trang","keywords":"Halogenation; Nitrile; Halogen; Tandem; Phosphine; Ligand (biochemistry)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001559887,0.0002368443,0.0002152605,0.0001682814,0.0003079406,0.000301278,0.0006807882,0.0003974449,0.002240417],"category_scores_gemma":[0.0002061705,0.0001366747,0.000175152,0.0001959407,0.0002218481,0.0003176417,0.0005289115,0.0004688513,0.0003859718],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006590111,"about_ca_system_score_gemma":0.0003402877,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002258858,"about_ca_topic_score_gemma":0.004011549,"domain_scores_codex":[0.9998692,0.0000169744,0.000004179536,0.00002224996,0.00002413435,0.00006329418],"domain_scores_gemma":[0.999939,0.00001342687,0.00001181875,0.00001124416,0.0000119279,0.00001263218],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000558413,0.00004729521,0.0003659806,0.0002283086,0.00004480332,0.0002929096,0.0004084027,0.001539568,0.9823949,0.005312741,0.001091722,0.007714865],"study_design_scores_gemma":[0.00003337197,0.0003376881,0.0009762401,0.00001045427,0.00001557155,0.0001611815,0.00006964196,0.001788855,0.9904806,0.0002655344,0.005840383,0.00002049173],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9893443,0.0007546892,0.001668035,0.0001990623,0.00005596174,0.00002032105,0.000105407,0.0000872384,0.007764941],"genre_scores_gemma":[0.9962354,0.0002383923,0.0004303057,0.00002742915,0.000003419737,0.000005720851,0.00009277109,0.00002059706,0.002945953],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002258858,"threshold_uncertainty_score":0.007494926,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00749321046710016,"score_gpt":0.2316189109016164,"score_spread":0.2241257004345163,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}