{"id":"W4415055230","doi":"10.1021/jacs.5c11608","title":"Modulating Hydrogen Exchange Capabilities by Heterogenizing Pd Nanoclusters onto Ni <sub>3</sub> C Multipods for Efficiently Driving the “Formaldehyde-Nitrate” Tandem Electrochemical System","year":2025,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Ammonia Synthesis and Nitrogen Reduction","field":"Chemical Engineering","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Light Source (Canada)","funders":"Basic and Applied Basic Research Foundation of Guangdong Province; National Natural Science Foundation of China; Science and Technology Foundation of Shenzhen City","keywords":"Nanoclusters; Catalysis; Electrochemistry; Tandem; Bifunctional; Faraday efficiency; Overpotential; Electrocatalyst","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004701511,0.0002431425,0.0001390756,0.00009205154,0.0001055979,0.0002715711,0.0003730018,0.0002735122,0.0007096173],"category_scores_gemma":[0.0001497123,0.0001332837,0.00009720425,0.00007191346,0.0002322402,0.0002496325,0.0002159995,0.0003046493,0.0002491888],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004181435,"about_ca_system_score_gemma":0.0001356151,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009623014,"about_ca_topic_score_gemma":0.002003977,"domain_scores_codex":[0.9999288,0.000003931641,0.000004987808,0.00002046293,0.00002567397,0.0000161111],"domain_scores_gemma":[0.9999523,0.000007533008,0.0000127256,0.000006355691,0.00001128223,0.000009757002],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006227761,0.00001909709,0.0001348482,0.00003233413,0.000007035906,0.00003480863,0.00001657277,0.0003315477,0.9963596,0.0001615944,0.0001753874,0.002664913],"study_design_scores_gemma":[0.00000644639,0.00005548729,0.0006792202,0.000001810439,0.000007135245,0.00003535911,0.00001518138,0.003913942,0.9942848,0.00002121598,0.0009744218,0.000004943317],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9907657,0.0003017714,0.00512346,0.00009524319,0.00003842862,0.00002878434,0.0001037366,0.0002465205,0.003296464],"genre_scores_gemma":[0.9957821,0.0001191479,0.003118026,0.00004115121,0.000004651271,0.00001653821,0.00005699087,0.00001923557,0.0008420589],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009623014,"threshold_uncertainty_score":0.003033817,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005643663888456352,"score_gpt":0.2130701776427336,"score_spread":0.2074265137542772,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}