{"id":"W4415055230","doi":"10.1021/jacs.5c11608","title":"Modulating Hydrogen Exchange Capabilities by Heterogenizing Pd Nanoclusters onto Ni <sub>3</sub> C Multipods for Efficiently Driving the “Formaldehyde-Nitrate” Tandem Electrochemical System","year":2025,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Ammonia Synthesis and Nitrogen Reduction","field":"Chemical Engineering","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Light Source (Canada)","funders":"Basic and Applied Basic Research Foundation of Guangdong Province; National Natural Science Foundation of China; Science and Technology Foundation of Shenzhen City","keywords":"Nanoclusters; Catalysis; Electrochemistry; Tandem; Bifunctional; Faraday efficiency; Overpotential; Electrocatalyst","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007436843,0.0003509809,0.0006455999,0.00003248476,0.0003930724,0.00007345143,0.0007302643,0.000156492,0.000001863783],"category_scores_gemma":[0.0003412374,0.0002263326,0.001179048,0.000457419,0.0003642941,0.0001409454,0.0001962034,0.0006741408,7.509494e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001075554,"about_ca_system_score_gemma":0.00009266809,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004119948,"about_ca_topic_score_gemma":0.000001613686,"domain_scores_codex":[0.9975867,0.0000998161,0.0008581157,0.000310776,0.000483627,0.000661018],"domain_scores_gemma":[0.9978746,0.0006267247,0.0008259394,0.0003421484,0.0001932007,0.0001373553],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000611061,0.0000587437,0.0003896872,0.0001405689,0.0003800279,2.629657e-7,0.0006971427,0.0005554557,0.9954693,0.00001731201,0.001161898,0.00106853],"study_design_scores_gemma":[0.0004572966,0.00003761702,0.00003181772,0.0002487186,0.0002139287,0.00005062495,0.003776796,0.05212327,0.942615,0.00001893662,0.0002005017,0.0002254333],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9909328,0.0007929093,0.006944443,0.0006566129,0.0002168264,0.0003517031,0.000009915545,0.0000688257,0.00002599918],"genre_scores_gemma":[0.9975324,0.00003023635,0.001652703,0.0002704937,0.0003884101,0.0000406118,0.000003494233,0.00005109516,0.00003057357],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05285421,"threshold_uncertainty_score":0.9229578,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005643663888456352,"score_gpt":0.2130701776427336,"score_spread":0.2074265137542772,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}