{"id":"W4415314285","doi":"10.1016/j.molstruc.2025.144453","title":"Synthesis of Fe(II) complexes containing amide-ligands derived from transformation of the CF3 group by hydrated ferrous chloride","year":2025,"lang":"en","type":"article","venue":"Journal of Molecular Structure","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":0,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Waterloo","funders":"Priority Academic Program Development of Jiangsu Higher Education Institutions; National Natural Science Foundation of China","keywords":"Isostructural; Amide; Metal; Group (periodic table); Substrate (aquarium); In situ; Chloride","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002461875,0.0001936183,0.0004728787,0.00006905557,0.000122881,0.000009573687,0.0004946392,0.0003141334,0.0002581107],"category_scores_gemma":[0.000236463,0.0001478099,0.0002135292,0.0002579605,0.0001782091,0.00007547523,0.00007079657,0.0007948881,1.876972e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008148527,"about_ca_system_score_gemma":0.0001270417,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002894977,"about_ca_topic_score_gemma":0.000009749621,"domain_scores_codex":[0.9985238,0.0001538893,0.0007744282,0.0001216524,0.0002486699,0.0001776069],"domain_scores_gemma":[0.9985535,0.0002979247,0.0006856127,0.0001894684,0.0002059283,0.00006758203],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006374452,0.00006322644,0.001395964,0.0000864028,0.0006550127,0.0000143994,0.0006067919,0.0007275153,0.9936456,0.00009317439,0.0007665563,0.001307894],"study_design_scores_gemma":[0.00146597,0.00007816159,0.002266346,0.0001331474,0.0005159708,0.00004350616,0.0002976052,0.0003114266,0.992698,0.000865764,0.001212784,0.000111309],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9962618,0.0009231647,0.0005340723,0.001080857,0.0005443018,0.0001337143,0.0001893668,0.000009746936,0.000322962],"genre_scores_gemma":[0.9991651,0.00006154081,0.0001620876,0.0004898601,0.00005910356,0.00000163471,0.00001687561,0.00001495179,0.00002891732],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002903214,"threshold_uncertainty_score":0.6027511,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01733074222243844,"score_gpt":0.3210646657362631,"score_spread":0.3037339235138246,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}