{"id":"W4415382676","doi":"10.1063/5.0293315","title":"Steady-state free precession NMR in the presence of heteronuclear couplings and decoupling: More than meets the eye","year":2025,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Advanced NMR Techniques and Applications","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"European Research Council; Azrieli Foundation; Israel Science Foundation","keywords":"Steady-state free precession imaging; Heteronuclear molecule; Precession; Free induction decay; Pulse (music); Pulse sequence; Relaxation (psychology)","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.003352551,0.0008407764,0.001438488,0.0007380877,0.0009009856,0.003137194,0.001597985,0.004194139,0.003621747],"category_scores_gemma":[0.003379187,0.000727842,0.0004255532,0.0004945386,0.003303752,0.009539388,0.002496665,0.006111718,0.002239001],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0009851209,"about_ca_system_score_gemma":0.00078681,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008612945,"about_ca_topic_score_gemma":0.001107535,"domain_scores_codex":[0.9987472,0.0002563252,0.00005806659,0.0002960638,0.0005699436,0.00007226524],"domain_scores_gemma":[0.9985591,0.0006650542,0.0001622128,0.0002640333,0.000218847,0.0001308639],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"theoretical_or_conceptual","study_design_scores_codex":[0.001070407,0.00009716488,0.001773836,0.003438445,0.0002667282,0.001644663,0.001920405,0.001757945,0.4288452,0.1419867,0.06632521,0.3508733],"study_design_scores_gemma":[0.0001356197,0.0003371469,0.002343703,0.00115942,0.0001407504,0.004112158,0.001055356,0.009119552,0.06554709,0.2038643,0.7118644,0.0003206007],"study_design_candidate":"theoretical_or_conceptual","study_design_consensus":null,"genre_codex":"review","genre_gemma":"empirical","genre_scores_codex":[0.0453829,0.4232192,0.3836004,0.089645,0.01313599,0.00005290294,0.0006419569,0.003787212,0.04053441],"genre_scores_gemma":[0.3475569,0.2719971,0.2510884,0.03789722,0.0186615,0.0001423027,0.0007430812,0.002455432,0.06945799],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.004194139,"threshold_uncertainty_score":0.01773018,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01265677872466917,"score_gpt":0.3067865731707507,"score_spread":0.2941297944460816,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}