{"id":"W4415655883","doi":"10.1039/d5ee01250c","title":"Transition metal coordination to degradation products in battery electrolytes revealed by NMR and EPR spectroscopy","year":2025,"lang":"en","type":"article","venue":"Energy & Environmental Science","topic":"Advanced Battery Materials and Technologies","field":"Engineering","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"European Research Council; Natural Sciences and Engineering Research Council of Canada; RWTH Aachen University; Royal Society; Faraday Institution","keywords":"Electron paramagnetic resonance; Transition metal; Electrolyte; Dissolution; Solvation; Metal; Coordination complex; Nuclear magnetic resonance spectroscopy","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001182876,0.000205126,0.0001442314,0.0001140361,0.0001348947,0.0003064832,0.00018048,0.0002951357,0.001239055],"category_scores_gemma":[0.0002281794,0.0001471061,0.00009148763,0.000111204,0.0001746181,0.0002421248,0.0001139142,0.0002690337,0.000218886],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001126947,"about_ca_system_score_gemma":0.0001121942,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006395616,"about_ca_topic_score_gemma":0.0005261776,"domain_scores_codex":[0.9999136,0.000008624952,0.000005457803,0.00002423056,0.0000253647,0.000022635],"domain_scores_gemma":[0.9999248,0.00001235073,0.00001625394,0.000009036681,0.00002599028,0.00001161642],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001015468,0.00001058232,0.0002318115,0.00001271037,0.000004094912,0.00006097256,0.00003549048,0.00006981577,0.9982812,0.00004299983,0.00002637906,0.001122438],"study_design_scores_gemma":[0.000004230639,0.0001344595,0.002014079,0.000003478529,0.000005707978,0.000110413,0.0000448686,0.0004794114,0.9965784,0.00004479934,0.0005768319,0.000003371651],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9969077,0.0003940569,0.001571145,0.00003649011,0.00001474848,0.000005922937,0.000121572,0.00002797596,0.0009204147],"genre_scores_gemma":[0.9971725,0.0002521651,0.0006288938,0.0000199122,0.000003240939,0.00000637674,0.0001940289,0.00001460274,0.001708324],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001239055,"threshold_uncertainty_score":0.004145086,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.002417809900033996,"score_gpt":0.1794640234388107,"score_spread":0.1770462135387767,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}