{"id":"W4415659095","doi":"10.1021/acs.inorgchem.5c03482","title":"Cu@Core in the Cu <sub>3</sub> C <sub>3</sub> Ring with 2-bdppmapy: A High-Quantum-Yield Planar Hexagonal Cu(I) Metallacycle","year":2025,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Nanocluster Synthesis and Applications","field":"Materials Science","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Innovation Cluster (Canada)","funders":"Beijing Municipal Natural Science Foundation; Beijing Municipal Commission of Education; National Natural Science Foundation of China","keywords":"Phenylacetylene; Photoluminescence; Excited state; Metallacycle; Planarity testing; Denticity; Planar; Charge (physics)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005266925,0.0002408713,0.0001888785,0.00008285857,0.0001468247,0.0002867494,0.0003891293,0.0002056634,0.001079795],"category_scores_gemma":[0.00009584973,0.0001698902,0.0000862546,0.0001331366,0.0001624863,0.0001473096,0.0003533596,0.000206878,0.0003958924],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000441047,"about_ca_system_score_gemma":0.0001738666,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001110523,"about_ca_topic_score_gemma":0.001602176,"domain_scores_codex":[0.9999378,0.000006643165,0.000003664934,0.00001870292,0.00001471633,0.00001846147],"domain_scores_gemma":[0.9999553,0.000003491714,0.00001573437,0.000007257106,0.000005741407,0.00001254992],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001659291,0.000015998,0.0001869324,0.0001544962,0.00001132891,0.0001096242,0.00006402124,0.0006762478,0.9927008,0.0007869293,0.0006719723,0.004455721],"study_design_scores_gemma":[0.0000189153,0.0002425595,0.001062055,0.000006296775,0.00001377093,0.0001455637,0.00002593283,0.001988217,0.9914863,0.00006017005,0.004939255,0.00001106618],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9892806,0.0004921004,0.00473727,0.00007364304,0.00003093097,0.00002998999,0.0001576163,0.0003715295,0.004826371],"genre_scores_gemma":[0.9925524,0.0001385466,0.004912691,0.00002711469,0.000004067213,0.00002599604,0.000113685,0.00004969219,0.002175845],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001110523,"threshold_uncertainty_score":0.00361228,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01251946952725887,"score_gpt":0.2213411484031771,"score_spread":0.2088216788759182,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}