{"id":"W4415693293","doi":"10.1021/acscatal.5c03642","title":"Interrupted Carbonyl–Olefin Metathesis of Cyclic, Aliphatic Ketones","year":2025,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"National Science Foundation Graduate Research Fellowship Program; National Institute of General Medical Sciences; Institute for Basic Science; Camille and Henry Dreyfus Foundation; Alfred P. Sloan Foundation; David and Lucile Packard Foundation","keywords":"Olefin metathesis; Metathesis; Olefin fiber; Catalysis; Reactivity (psychology); Salt metathesis reaction","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003548496,0.0002647691,0.0006515654,0.0001416611,0.00004953918,0.00002268093,0.0006252024,0.0001828513,0.001472508],"category_scores_gemma":[0.001304575,0.0002598102,0.0002974179,0.000689202,0.0001634481,0.00005525145,0.0002325314,0.0001553958,0.00002397396],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001054648,"about_ca_system_score_gemma":0.00008852861,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002733998,"about_ca_topic_score_gemma":0.00001718891,"domain_scores_codex":[0.9983213,0.00005228636,0.0006193702,0.000454782,0.0002772519,0.0002750355],"domain_scores_gemma":[0.9976392,0.000692645,0.0002370204,0.001262832,0.00009510223,0.00007316035],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001924573,0.0001371231,0.001590473,0.0003117942,0.0008727305,0.00000507068,0.0003609589,0.000003522552,0.9770702,0.00008127229,0.0002303235,0.01931726],"study_design_scores_gemma":[0.0003013288,0.000003201596,0.0001751456,0.000112635,0.001048452,0.000006073912,0.0006295477,0.0001176419,0.9952152,0.0004489926,0.00173614,0.000205677],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9513475,0.0009099438,0.0005229213,0.0004953551,0.00009483073,0.00004894933,0.0000317438,0.0001258227,0.04642298],"genre_scores_gemma":[0.9895844,0.00005162812,0.002629514,0.00005964621,0.00004416393,0.00003050746,0.00005266784,0.00003197206,0.007515515],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03890746,"threshold_uncertainty_score":0.9999854,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01000447872278259,"score_gpt":0.2806578110063284,"score_spread":0.2706533322835458,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}