{"id":"W4415693293","doi":"10.1021/acscatal.5c03642","title":"Interrupted Carbonyl–Olefin Metathesis of Cyclic, Aliphatic Ketones","year":2025,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"National Science Foundation Graduate Research Fellowship Program; National Institute of General Medical Sciences; Institute for Basic Science; Camille and Henry Dreyfus Foundation; Alfred P. Sloan Foundation; David and Lucile Packard Foundation","keywords":"Olefin metathesis; Metathesis; Olefin fiber; Catalysis; Reactivity (psychology); Salt metathesis reaction","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001596538,0.0004979852,0.0001721421,0.0002765995,0.00013113,0.0002383444,0.0002882674,0.0001900562,0.001541142],"category_scores_gemma":[0.0001615145,0.0001140558,0.0002172621,0.0001471367,0.0001660527,0.0002891082,0.0003131805,0.0003959879,0.0005737842],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002810592,"about_ca_system_score_gemma":0.0002213917,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003042603,"about_ca_topic_score_gemma":0.0008463886,"domain_scores_codex":[0.9998764,0.00001294438,0.000008591022,0.00002331908,0.00002584217,0.00005288338],"domain_scores_gemma":[0.9999499,0.000008637982,0.00001234962,0.000009925594,0.000007098794,0.00001192141],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001687293,0.00009863438,0.0003434671,0.0001817936,0.00002744084,0.001061243,0.0001576279,0.0007619058,0.977836,0.002948115,0.0003612817,0.01605385],"study_design_scores_gemma":[0.00001805033,0.0003412013,0.0009682206,0.00001063057,0.00001418698,0.000340129,0.00002387352,0.0007559814,0.9901493,0.0002239394,0.007145127,0.000009430113],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9454769,0.002202609,0.01442189,0.0001576849,0.0001473073,0.0001282019,0.0005006058,0.0002499674,0.03671466],"genre_scores_gemma":[0.9923746,0.0008869653,0.00290097,0.00003050681,0.00001424419,0.0000231687,0.0001460599,0.00001960874,0.003603866],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001541142,"threshold_uncertainty_score":0.005155623,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01000447872278259,"score_gpt":0.2806578110063284,"score_spread":0.2706533322835458,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}