{"id":"W4415881495","doi":"10.1039/d5cc05315c","title":"Excited-state structural conformations of Fe-amido photosensitizers revealed by picosecond X-ray absorption spectroscopy","year":2025,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"Natural Sciences and Engineering Research Council of Canada; U.S. Department of Energy","keywords":"Photoexcitation; Picosecond; Spectroscopy; Ultrashort pulse; Ultrafast laser spectroscopy; Absorption (acoustics); Population","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005999081,0.0001214445,0.00005809431,0.00008933374,0.0001744942,0.000154489,0.0002342683,0.0002335973,0.003611607],"category_scores_gemma":[0.0001409699,0.00009325205,0.00007881398,0.0000903101,0.0001898517,0.0001877917,0.00006830572,0.0005827312,0.0002402545],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003552376,"about_ca_system_score_gemma":0.00008593515,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006748755,"about_ca_topic_score_gemma":0.001057872,"domain_scores_codex":[0.9999794,0.000001923193,6.731923e-7,0.000006226318,0.000004570466,0.000007266069],"domain_scores_gemma":[0.9999669,0.00001158535,0.000008149687,0.000004943907,0.000003524894,0.000004915661],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001913447,0.0000452688,0.000578134,0.0000381899,0.00001036177,0.0001110688,0.00008996545,0.0008396629,0.992393,0.00136569,0.000323999,0.00401331],"study_design_scores_gemma":[0.0000268414,0.0003477564,0.02357858,0.00001377329,0.00001534205,0.0002320125,0.00009093829,0.007980814,0.9644304,0.0005881514,0.002677433,0.00001796048],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9938439,0.0003579218,0.002284527,0.00007814507,0.000008975363,0.000006329276,0.0001885534,0.00007215929,0.003159522],"genre_scores_gemma":[0.9978201,0.0001429788,0.0006928829,0.0000281243,0.000001376492,0.00000903218,0.000211813,0.00001003914,0.001083488],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003611607,"threshold_uncertainty_score":0.01208198,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01260218088223475,"score_gpt":0.27268801379342,"score_spread":0.2600858329111853,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}