{"id":"W4415912351","doi":"10.1039/d5cc05272f","title":"Detecting impurity-specific effects on structure and radiolytic hydrogen production in aluminum hydroxide","year":2025,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Bauxite Residue and Utilization","field":"Engineering","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"Pacific Northwest National Laboratory; Basic Energy Sciences; Natural Sciences and Engineering Research Council of Canada; Office of Science; Battelle; TRIUMF; U.S. Department of Energy","keywords":"Gibbsite; Radiolysis; Solvated electron; Hydroxide; Hydrogen; Hydrogen production; Diamagnetism; Electron","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006709072,0.00009946163,0.0001168679,0.0001098863,0.00007502694,0.00001768713,0.000212734,0.00009693332,0.000001334306],"category_scores_gemma":[0.0000948351,0.0001082944,0.00002008969,0.0003652719,0.00004797505,0.00006385881,0.00007649149,0.0003204406,0.000002427306],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000101023,"about_ca_system_score_gemma":0.000008095266,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000004332407,"about_ca_topic_score_gemma":0.00001626613,"domain_scores_codex":[0.9994861,0.00003841131,0.0001564481,0.0001411091,0.00004993445,0.0001279248],"domain_scores_gemma":[0.9991343,0.0001770794,0.00001625792,0.000627799,0.00001502013,0.00002951798],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000006274634,0.00002781961,0.001368306,0.0001604678,0.00002353227,6.030195e-7,0.0002215781,0.0006775199,0.9408464,0.0009089977,0.0002326501,0.05552582],"study_design_scores_gemma":[0.0002076683,0.000005674784,0.002228372,0.0001626381,0.0000111352,0.000004545034,0.00002257512,0.009753069,0.9830206,0.002277704,0.002188731,0.0001172858],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9943034,0.003491498,0.00006828198,0.0003566297,0.00006415067,0.0002070865,0.000001735582,0.0001323104,0.001374885],"genre_scores_gemma":[0.9987813,0.0006300345,0.0004453141,0.00002671599,0.00003287114,0.00002777996,0.00002613838,0.00001169651,0.00001809868],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05540853,"threshold_uncertainty_score":0.4416116,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008853128134959429,"score_gpt":0.2301079736849055,"score_spread":0.221254845549946,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}