{"id":"W4416008844","doi":"10.1021/acsomega.5c09724","title":"Mechanistic Insights into the Coupling of Hydrosilanes and Alcohol-Amines for Hydrogen Production","year":2025,"lang":"en","type":"article","venue":"ACS Omega","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Alliance de recherche numérique du Canada","keywords":"Disproportionation; Hydride; Nucleophile; Hydrogen; Reaction mechanism; Coupling reaction; Radical; Chlorobenzene; Nucleophilic substitution","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002264482,0.0004458329,0.0001459437,0.000151317,0.0001573422,0.0002595403,0.0004166261,0.0004322006,0.005092822],"category_scores_gemma":[0.0001626941,0.0002155372,0.0002834833,0.00007833653,0.0002487667,0.0007504184,0.0002048601,0.0006548735,0.0008509532],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003096233,"about_ca_system_score_gemma":0.0001942126,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000392474,"about_ca_topic_score_gemma":0.0008301238,"domain_scores_codex":[0.99993,0.000007347193,0.000003397957,0.0000159381,0.00002303944,0.00002025886],"domain_scores_gemma":[0.9999492,0.00002086896,0.00001073252,0.000005109819,0.00000728967,0.000006827932],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002228697,0.00008519137,0.0009026559,0.0006496076,0.0000311154,0.0005644769,0.0001449006,0.002649084,0.9767101,0.008833637,0.0004582642,0.008748044],"study_design_scores_gemma":[0.0000170554,0.0002155549,0.00177633,0.00002732832,0.00001735461,0.0002280678,0.0001386062,0.01238924,0.9769696,0.001842991,0.00636343,0.00001448354],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9219227,0.007204812,0.03581695,0.0009360189,0.0001329621,0.0001805292,0.001233873,0.0003189277,0.03225319],"genre_scores_gemma":[0.98782,0.002461232,0.005597622,0.00009220841,0.00001642971,0.00004310949,0.0002523988,0.00002437854,0.003692479],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005092822,"threshold_uncertainty_score":0.01703721,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01063970423612661,"score_gpt":0.2473812642732159,"score_spread":0.2367415600370893,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}