{"id":"W4416181469","doi":"10.1139/cjc-2025-0205","title":"Evaluation of H <sub>2</sub> O <sub>2</sub> /HFIP as a convenient sulfoxidation reagent for boronate containing thioethers","year":2025,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"Natural Sciences and Engineering Research Council of Canada; Mitacs","keywords":"Reagent; Thioether; Oxidizing agent; Sulfoxide; Alcohol; Dimethyl sulfoxide; Sulfur","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001204037,0.0002305258,0.0004054621,0.0001049471,0.0001680274,0.00005526494,0.0002860956,0.0003143284,0.0002332165],"category_scores_gemma":[0.001648699,0.0002346389,0.0003430249,0.0001775819,0.0001478012,0.0001179315,0.00001821397,0.0003869425,0.000003462788],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001253479,"about_ca_system_score_gemma":0.003817199,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003494011,"about_ca_topic_score_gemma":0.0005456654,"domain_scores_codex":[0.9979752,0.00003804755,0.0008095941,0.0002632403,0.0005309648,0.0003829803],"domain_scores_gemma":[0.9970079,0.0002620682,0.0007214837,0.0002951611,0.001233233,0.0004801466],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007788577,0.00004447347,0.0001929411,0.0002011151,0.0002800303,0.000008219115,0.0001872256,0.0001589403,0.9590365,0.00003644151,0.0008863296,0.03888988],"study_design_scores_gemma":[0.001333599,0.00002273729,0.0001687745,0.0006149198,0.0004788355,0.00005058077,0.0009306124,0.0003541916,0.9916756,0.0007519395,0.003412475,0.0002057425],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.988261,0.0009201554,0.00009347076,0.0006614026,0.0002091341,0.0001413055,0.00007992326,0.00001135433,0.009622226],"genre_scores_gemma":[0.9993476,0.0001062715,0.00003893238,0.00008473261,0.0002290508,0.00003112656,0.00005665761,0.00002839432,0.00007729097],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03868414,"threshold_uncertainty_score":0.9568297,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02113997621128156,"score_gpt":0.2609728512355592,"score_spread":0.2398328750242776,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}