{"id":"W4416423863","doi":"10.1016/j.poly.2025.117891","title":"Contrasting the reactions of diphenylamine and diphenylphosphine with the 1,3-dicholoro-1,3-bis(dimethylamino)propenium ion","year":2025,"lang":"en","type":"article","venue":"Polyhedron","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":false,"ca_institutions":"Saint Mary's University; Mount Saint Vincent University","funders":"Natural Sciences and Engineering Research Council of Canada; Dalhousie University; Saint Mary’s University; Canada Foundation for Innovation; Nova Scotia Research Innovation Trust","keywords":"Diphenylamine; Hexafluorophosphate; Diphenylphosphine; Iminium; Reactivity (psychology); Ion; Salt (chemistry); Fluoride; Methoxide","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001773948,0.0001919176,0.0001139577,0.0001339112,0.0001487265,0.0003505111,0.0003283228,0.0003176399,0.001650792],"category_scores_gemma":[0.0002897929,0.0001212494,0.0001072394,0.00008722409,0.0001871052,0.0002632534,0.0001996476,0.0002880792,0.0003775728],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001767618,"about_ca_system_score_gemma":0.0001824819,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004500937,"about_ca_topic_score_gemma":0.0008616659,"domain_scores_codex":[0.9998496,0.00002749022,0.000009020639,0.00004846672,0.00002924277,0.00003623501],"domain_scores_gemma":[0.9998814,0.00004373034,0.00002913755,0.00001307213,0.00001444193,0.00001832266],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003896668,0.00002327297,0.0001783927,0.0001100496,0.000006372867,0.0001354223,0.00005736631,0.0001006195,0.9946005,0.0007919999,0.00008891053,0.003517315],"study_design_scores_gemma":[0.000008760117,0.0001054199,0.0002483656,0.000002609163,0.000003650395,0.0001417945,0.00001112728,0.000222815,0.9974558,0.00002921608,0.001767777,0.000002671099],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9759675,0.001965538,0.0065703,0.00009816352,0.00007472646,0.00007029931,0.0001851621,0.00006470102,0.01500363],"genre_scores_gemma":[0.9928524,0.0004820145,0.002615488,0.0000237727,0.000006032871,0.0000162531,0.0001047605,0.00001514718,0.003884168],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001650792,"threshold_uncertainty_score":0.00552243,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006345342749531539,"score_gpt":0.2091584718786148,"score_spread":0.2028131291290833,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}