{"id":"W4416530844","doi":"10.1002/cctc.202501239","title":"Glycerol Carbonate from Dimethyl Carbonate and Glycerol Over TBD‐Functionalized SBA‐16","year":2025,"lang":"en","type":"article","venue":"ChemCatChem","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"SiliCycle (Canada); Université Laval","funders":"","keywords":"Glycerol; Dimethyl carbonate; Transesterification; Catalysis; Carbonate; Biodiesel; Heterogeneous catalysis; Endothermic process","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001358172,0.0005317988,0.0002534085,0.0003204675,0.0001107424,0.000211011,0.0001937968,0.0002109549,0.001114637],"category_scores_gemma":[0.00009804357,0.0001878356,0.0003021677,0.0001723788,0.0001504255,0.0001801728,0.0002053272,0.0002497597,0.0005528253],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002409105,"about_ca_system_score_gemma":0.0002149513,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001191409,"about_ca_topic_score_gemma":0.002429506,"domain_scores_codex":[0.9999189,0.000007679357,0.000008155049,0.00001524551,0.0000236627,0.00002634941],"domain_scores_gemma":[0.9999537,0.000005733525,0.00001110181,0.000004361844,0.0000111573,0.00001386425],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005728098,0.000008812819,0.0000832088,0.00004689538,0.000006076656,0.00002749284,0.000005503341,0.00009956206,0.9985839,0.00003510973,0.0000175318,0.001028565],"study_design_scores_gemma":[0.000003769134,0.00006777079,0.0004084294,0.000003865164,0.000009186145,0.00003794596,0.000006580756,0.0005938917,0.9980397,0.000006206463,0.0008193384,0.000003353063],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9940572,0.001113503,0.002450747,0.00003724555,0.00004244551,0.00001979083,0.0001801047,0.0001091067,0.001989855],"genre_scores_gemma":[0.994889,0.0005246259,0.002583856,0.00001976886,0.000005314381,0.00001296378,0.0002089917,0.00002046356,0.001735062],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001191409,"threshold_uncertainty_score":0.003728807,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006610044640749207,"score_gpt":0.2345560005641709,"score_spread":0.2279459559234217,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}