{"id":"W4417102040","doi":"10.1002/ange.202522424","title":"Packing Order Control in Conductive Metal–Organic Frameworks by Tuning Ligand Oxidation State","year":2025,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ministry of Education and Child Care","funders":"National Key Research and Development Program of China; Chinese Academy of Sciences; National Natural Science Foundation of China","keywords":"Oxidation state; Ligand (biochemistry); Lanthanide; Electrical conductor; Coordination complex; Porosity; Metal; Topology (electrical circuits)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001029413,0.0002185294,0.00008725353,0.000132075,0.0001444411,0.0002837448,0.0002652022,0.0001674792,0.0004857371],"category_scores_gemma":[0.0002055103,0.0001000033,0.00006520477,0.0001308211,0.0002098199,0.0002184827,0.0001679246,0.0001914052,0.00009214482],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004406621,"about_ca_system_score_gemma":0.0001759864,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001179197,"about_ca_topic_score_gemma":0.002018059,"domain_scores_codex":[0.9999205,0.00000808044,0.000004240521,0.00001898231,0.00001811565,0.0000299755],"domain_scores_gemma":[0.9999369,0.00001748461,0.00002092873,0.000006178921,0.000008073102,0.00001033208],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001113884,0.00003447763,0.0002568581,0.00006149047,0.000006064801,0.00005445468,0.00004202285,0.001839035,0.9906978,0.001180193,0.000145583,0.005570777],"study_design_scores_gemma":[0.00002030983,0.00009036671,0.0008185637,0.000004227886,0.000004414523,0.00003318264,0.00001929373,0.007745458,0.9896319,0.0001403007,0.001480555,0.00001142252],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9965441,0.0003157408,0.001976563,0.0000328515,0.000008498359,0.000007180598,0.00003985884,0.00009627997,0.0009789326],"genre_scores_gemma":[0.9987497,0.00009775488,0.0008906041,0.000008846216,0.000001753487,0.000004035446,0.00002134376,0.000007235538,0.0002185799],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001179197,"threshold_uncertainty_score":0.003197193,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01060818071459313,"score_gpt":0.246938523029425,"score_spread":0.2363303423148319,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}