{"id":"W4417221567","doi":"10.1002/ejoc.202500894","title":"Intra‐ and Intermolecular Glycosylation of <scp>d</scp> ‐Idopyranosyl and 6‐Deoxy‐ <scp>d</scp> ‐ <i>ido</i> ‐heptopyranosyl Donors: Toward the Repeating Unit of <i>Campylobacter jejuni</i> HS:4c Capsular Polysaccharide","year":2025,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Institut National de la Recherche Scientifique; Université du Québec à Chicoutimi","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Disaccharide; Glycosylation; Intramolecular force; Intermolecular force; Anomer; Carbohydrate conformation; Protecting group","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009207692,0.0003900061,0.0000833054,0.00007854672,0.00008263739,0.000164239,0.0001565087,0.0001691838,0.0007008407],"category_scores_gemma":[0.00008712491,0.00008549263,0.0001164898,0.0001174992,0.0001184721,0.0001914132,0.0002245035,0.0003767011,0.0002600042],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001991882,"about_ca_system_score_gemma":0.0002791281,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004895878,"about_ca_topic_score_gemma":0.0007515323,"domain_scores_codex":[0.9999394,0.000009804392,0.000003545664,0.00001207884,0.00001103312,0.00002395829],"domain_scores_gemma":[0.9999578,0.00000395738,0.0000141226,0.000006295425,0.000005542769,0.00001243653],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008695002,0.00002993637,0.0001293975,0.00004057737,0.00000488408,0.00009750337,0.00002554915,0.0002400698,0.9954659,0.0004064084,0.00007248489,0.003400302],"study_design_scores_gemma":[0.000004638604,0.0002156005,0.0003607983,0.000002545719,0.000006006292,0.00009080667,0.00001351327,0.000502444,0.9971034,0.00003313662,0.001662707,0.000004432641],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9891227,0.0003843713,0.005213012,0.00005448229,0.00001797959,0.00003972727,0.0001644413,0.00004421242,0.004959126],"genre_scores_gemma":[0.9921434,0.0005290335,0.004696553,0.00004267627,0.000004542932,0.00002742374,0.000235001,0.00001682121,0.002304706],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007008407,"threshold_uncertainty_score":0.002344489,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007987186450273614,"score_gpt":0.1993325376684302,"score_spread":0.1913453512181566,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}