{"id":"W4417260859","doi":"10.26434/chemrxiv-2025-dwn7n","title":"Synthesis and Redox Properties of a Thermally Stable bis-N-Heterocyclic Carbene Adduct of Phosphorus Mononitride","year":2025,"lang":"","type":"preprint","venue":"ChemRxiv","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia; University of Victoria","funders":"","keywords":"Dication; Adduct; Carbene; Redox; Dimer; Thermal stability; Phosphorus; Electrochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001008731,0.0001579112,0.000115809,0.00007989867,0.0001430404,0.000170625,0.0002060371,0.0002459726,0.0007489738],"category_scores_gemma":[0.000124896,0.00007507097,0.00008617312,0.00008210569,0.0001411056,0.0001634714,0.0001311447,0.0002412687,0.0002170714],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000192834,"about_ca_system_score_gemma":0.0001080012,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005335723,"about_ca_topic_score_gemma":0.001189387,"domain_scores_codex":[0.9999081,0.000007757859,0.000004874229,0.00002942756,0.00003590805,0.00001397218],"domain_scores_gemma":[0.9999552,0.000005534351,0.00001385084,0.000006578125,0.000009847126,0.000008948049],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000263925,0.000005515884,0.00009581935,0.00002439348,0.00000266597,0.0000377271,0.00001907387,0.00008484923,0.9984041,0.00007494162,0.00001724014,0.001207386],"study_design_scores_gemma":[0.000002674603,0.00009285539,0.000793778,0.000001178046,0.000003741672,0.00009337532,0.00000846332,0.0002720396,0.9977971,0.00001309192,0.000918471,0.000003397853],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9957554,0.0006150155,0.001724272,0.00003534219,0.000007565065,0.00001946407,0.0001673495,0.00003101044,0.001644511],"genre_scores_gemma":[0.9959299,0.0002471422,0.002234153,0.00001297664,0.000003890178,0.000009461949,0.000146951,0.00001287796,0.001402585],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007489738,"threshold_uncertainty_score":0.002505541,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0227018295067215,"score_gpt":0.2202571556002435,"score_spread":0.197555326093522,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}