{"id":"W4417432410","doi":"10.3762/bjoc.21.210","title":"Total synthesis of asperdinones B, C, D, E and terezine D","year":2025,"lang":"en","type":"article","venue":"Beilstein Journal of Organic Chemistry","topic":"Synthesis of Indole Derivatives","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Indole test; Negishi coupling; Total synthesis; Prenylation; Epimer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008213505,0.0004680667,0.0003707418,0.0004851412,0.0002599278,0.0002855964,0.0002734705,0.0002293709,0.002797179],"category_scores_gemma":[0.00009470262,0.0001440518,0.0002949858,0.0004419121,0.0001588004,0.0002141761,0.0003584977,0.0004914491,0.001193392],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002616519,"about_ca_system_score_gemma":0.0005257584,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009059336,"about_ca_topic_score_gemma":0.001183219,"domain_scores_codex":[0.9999292,0.000006438039,0.000006931774,0.00001809566,0.00001586493,0.00002349838],"domain_scores_gemma":[0.9999318,0.000005424475,0.0000085705,0.00001163066,0.00001252627,0.00003006726],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001821272,0.00009174665,0.0001795177,0.000422339,0.00003588303,0.0005876124,0.0001179874,0.001039281,0.9610165,0.001689591,0.0003763306,0.03426107],"study_design_scores_gemma":[0.0001102039,0.001033949,0.002393378,0.00004095179,0.00008234111,0.0007322225,0.00007504883,0.0007777591,0.9344149,0.0007118038,0.05958094,0.00004663791],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8631331,0.01389636,0.04712624,0.0002861859,0.0002733463,0.0008280601,0.004580542,0.0008833323,0.06899289],"genre_scores_gemma":[0.9546965,0.005871105,0.01922599,0.0001300301,0.00002111317,0.000159116,0.001676746,0.0000629889,0.01815623],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002797179,"threshold_uncertainty_score":0.009357512,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004760480212743423,"score_gpt":0.2147047928510001,"score_spread":0.2099443126382567,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}