{"id":"W4417498481","doi":"10.1021/jacs.5c15827","title":"Asymmetrical Substitution Manipulates Stacking Modes in 2D Conductive MOF Crystals","year":2025,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ministry of Education and Child Care","funders":"Fundamental Research Funds for the Central Universities; National Key Research and Development Program of China; National Natural Science Foundation of China","keywords":"Stacking; van der Waals force; Nanocrystalline material; Anisotropy; Rational design; Electrical conductor; Crystallinity; Modulation (music)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008563272,0.0002433648,0.0001427144,0.0001683176,0.0001578785,0.0002886772,0.0002361165,0.000265601,0.0004585694],"category_scores_gemma":[0.0001807518,0.000124987,0.0001017968,0.0001454372,0.0002448217,0.0002610415,0.0002194617,0.0003053361,0.0001080605],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003368779,"about_ca_system_score_gemma":0.0002191805,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007231417,"about_ca_topic_score_gemma":0.001700441,"domain_scores_codex":[0.9999226,0.000008254381,0.000005591024,0.00001925309,0.000020386,0.00002385197],"domain_scores_gemma":[0.9999321,0.0000196917,0.00002198038,0.00000784457,0.000008798104,0.000009642271],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003350084,0.00001634044,0.0001692728,0.00005263185,0.000005149132,0.00005946704,0.00003123001,0.0008646353,0.9936715,0.001231429,0.00008653362,0.003778341],"study_design_scores_gemma":[0.00001270481,0.00006007302,0.0005998079,0.000003995408,0.000004422751,0.00008248918,0.00001671195,0.004326576,0.9931249,0.0001353144,0.001621836,0.00001120223],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9916298,0.0003789198,0.005768854,0.00005731793,0.00001994537,0.00001300715,0.0001005021,0.0001073752,0.001924297],"genre_scores_gemma":[0.9937857,0.000268118,0.005426667,0.0000271134,0.000004801805,0.00001853058,0.00004759948,0.00001583231,0.0004055557],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007231417,"threshold_uncertainty_score":0.002444208,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02096475146765103,"score_gpt":0.2808553774231923,"score_spread":0.2598906259555412,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}