{"id":"W4712465","doi":"10.1136/hrt.35.6.610","title":"HIGH RESOLUTION ROVIBRATIONAL SPECTRA OF FIVE-MEMBERED RINGS WITH HETEROATOMS: NEW RESULTS FROM THE FAR-INFRARED BEAMLINE OF THE CANADIAN LIGHT SOURCE","year":2007,"lang":"en","type":"article","venue":"","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Beamline; Heteroatom; Rotational–vibrational spectroscopy; Far infrared; Physics; Spectral line; Ring (chemistry); Astronomy; Chemistry; Optics; Beam (structure)","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003475109,0.0003730459,0.0003570964,0.0005076978,0.001103163,0.0005564187,0.001272565,0.0004832506,0.003452556],"category_scores_gemma":[0.0002325564,0.0002350789,0.0002454139,0.001027358,0.0007320888,0.000585305,0.0003135815,0.0006244569,0.0003636745],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001058547,"about_ca_system_score_gemma":0.0004873791,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.08910274,"about_ca_topic_score_gemma":0.150111,"domain_scores_codex":[0.9997318,0.00001529862,0.000003021281,0.00004454818,0.0001251526,0.00008017379],"domain_scores_gemma":[0.9997844,0.00003610131,0.00003166395,0.00003400971,0.0000766407,0.00003719092],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006871917,0.00009622387,0.002261833,0.0001703639,0.00007847275,0.0002435935,0.0004000696,0.001143609,0.9832904,0.0006200108,0.00292058,0.008087619],"study_design_scores_gemma":[0.0001441278,0.0003104672,0.07107233,0.00003315167,0.0001721717,0.0006096226,0.0003845245,0.006181864,0.9042215,0.0004065755,0.01638044,0.00008320661],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9814804,0.002510136,0.004046649,0.000143934,0.00001980153,0.00002446203,0.002113128,0.000259857,0.009401619],"genre_scores_gemma":[0.9869956,0.001389044,0.00565326,0.0000709266,0.00001367733,0.00001256446,0.001992799,0.00006853677,0.003803614],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08910274,"threshold_uncertainty_score":0.1771682,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007138383817828433,"score_gpt":0.1937640027997263,"score_spread":0.1866256189818978,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}