{"id":"W54619825","doi":"10.1002/047084289x.rd062.pub3","title":"Di‐ <i>Tert</i> ‐Butyl Hyponitrite","year":2021,"lang":"en","type":"other","venue":"Encyclopedia of Reagents for Organic Synthesis","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Chemistry; Benzophenone; Sodium methoxide; Toluene; Hexane; Reagent; Proton NMR; Medicinal chemistry; Pentane; Nuclear chemistry; Organic chemistry; Methanol","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001065278,0.0005595502,0.0009994672,0.0001610995,0.00005990624,0.0000231023,0.000722661,0.000905337,0.09990367],"category_scores_gemma":[0.002930319,0.000564289,0.0005626119,0.000271033,0.0001466324,0.00003410104,0.0001535762,0.0003730637,0.0001835252],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001469062,"about_ca_system_score_gemma":0.000215257,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001833801,"about_ca_topic_score_gemma":0.00004299465,"domain_scores_codex":[0.9974615,0.00002921642,0.0006643489,0.0007997605,0.0005191964,0.0005259634],"domain_scores_gemma":[0.996664,0.001254815,0.0005610723,0.001152262,0.00007414986,0.0002936902],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00003560738,0.000467951,0.0001633391,0.001580774,0.000794178,0.00002657106,0.00003535323,7.265922e-8,0.2690729,0.00002602913,0.7078651,0.01993212],"study_design_scores_gemma":[0.0002705754,0.000007997282,0.000009884211,0.0007475311,0.0003846511,0.00000974899,0.00002949339,0.00000280553,0.247205,0.00006638451,0.7508496,0.0004163163],"study_design_candidate":"not_applicable","study_design_consensus":"not_applicable","genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.001364955,0.002272012,0.000212596,0.00009672639,0.0004978995,0.0003916155,0.001067621,0.000275839,0.9938207],"genre_scores_gemma":[0.001923045,0.004074674,0.001699813,0.00005377192,0.001158386,0.0004129268,0.0003577687,0.001185692,0.9891339],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.09972014,"threshold_uncertainty_score":0.9996809,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0112892195320044,"score_gpt":0.2418863212660489,"score_spread":0.2305971017340445,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}