{"id":"W6884436152","doi":"10.1021/es303152m.s001","title":"Polyfluorinated Amides\\nas a Historical PFCA Source\\nby Electrochemical Fluorination of Alkyl Sulfonyl Fluorides","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Per- and polyfluoroalkyl substances research","field":"Environmental Science","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Hydrolysis; Amide; Sulfonyl; Alkyl; Sulfonamide; Volatilisation; Decarboxylation","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003560749,0.0006846944,0.0003105152,0.0003793352,0.0002406163,0.0003290438,0.0002679387,0.0003152397,0.001936505],"category_scores_gemma":[0.0003625773,0.0002141639,0.0002651236,0.0002853269,0.0002418555,0.0004066748,0.0001668768,0.0003071006,0.0008793858],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003926312,"about_ca_system_score_gemma":0.0002767776,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001883387,"about_ca_topic_score_gemma":0.003653597,"domain_scores_codex":[0.9995573,0.00003977086,0.00002410854,0.0001423223,0.0001792556,0.00005724252],"domain_scores_gemma":[0.9997639,0.00002967411,0.00003991988,0.00002756255,0.0001243498,0.00001465905],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003761415,0.000006105364,0.0002269806,0.00004590912,0.000003404823,0.00002812222,0.00001128321,0.00003569642,0.9971404,0.00003045831,0.00003765377,0.002396448],"study_design_scores_gemma":[0.00000163959,0.0001062092,0.001091348,0.000005971136,0.000006610593,0.0000880526,0.00001187261,0.0001560767,0.9950729,0.000009832524,0.003445223,0.000004159883],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9561726,0.005382052,0.02593137,0.000113455,0.0001227925,0.0001752196,0.001585142,0.0003399719,0.01017746],"genre_scores_gemma":[0.9451206,0.005053993,0.03535163,0.0001420248,0.00004902935,0.0001479426,0.001757118,0.0001197605,0.01225791],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001936505,"threshold_uncertainty_score":0.00647825,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02097728474092694,"score_gpt":0.2428601853905642,"score_spread":0.2218829006496373,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}