{"id":"W6884457858","doi":"10.1021/ja9074776.s001","title":"&lt;i&gt;In Situ&lt;/i&gt; Generation of Zinc Carbenoids from Diazo Compounds and Zinc Salts: Asymmetric Synthesis of 1,2,3-Substituted Cyclopropanes","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Natural Resources Canada","funders":"","keywords":"Zinc; Diazo; Enantioselective synthesis; Zinc compounds; Cyclopropanation","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00008713068,0.0003345932,0.0005826666,0.0002991534,0.00006991191,0.00003227576,0.0003121813,0.0003298802,0.00904432],"category_scores_gemma":[0.001533836,0.0002866312,0.0001269974,0.000440584,0.00004039782,0.0002586016,0.000155747,0.0001366479,0.000123266],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002104238,"about_ca_system_score_gemma":0.000124081,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006052789,"about_ca_topic_score_gemma":0.0003521522,"domain_scores_codex":[0.9978816,0.00006179434,0.0006702016,0.0005640563,0.0004938452,0.0003285331],"domain_scores_gemma":[0.9978371,0.0006698091,0.0004799414,0.0006036137,0.0002717192,0.0001378289],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003858019,0.00009246588,0.0002306299,0.000434161,0.00005750246,0.00001520907,0.0001261815,0.000006800342,0.9739596,0.0000685701,0.001674993,0.02329532],"study_design_scores_gemma":[0.0007957496,0.00002535764,0.004503489,0.001732611,0.0000604077,0.00001135189,0.00003303726,0.0001704365,0.9828503,0.00008267651,0.009379064,0.0003555494],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8840362,0.003304593,0.0000215858,0.00006134224,0.0001262323,0.0003111411,0.1012473,0.0001576536,0.01073392],"genre_scores_gemma":[0.9875303,0.0001405249,0.0004108141,0.000008908853,0.0002382636,0.0001516943,0.01129701,0.00005976662,0.0001627227],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1034941,"threshold_uncertainty_score":0.9999586,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02496508741968612,"score_gpt":0.2279449981562855,"score_spread":0.2029799107365994,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}