{"id":"W6884464546","doi":"10.1021/ja203214f.s002","title":"Dihydrogen Activation with &lt;sup&gt;&lt;i&gt;t&lt;/i&gt;&lt;/sup&gt;Bu&lt;sub&gt;3&lt;/sub&gt;P/B(C&lt;sub&gt;6&lt;/sub&gt;F&lt;sub&gt;5&lt;/sub&gt;)&lt;sub&gt;3&lt;/sub&gt;: A Chemically Competent Indirect Mechanism via in Situ-Generated &lt;i&gt;p&lt;/i&gt;-&lt;sup&gt;&lt;i&gt;t&lt;/i&gt;&lt;/sup&gt;Bu&lt;sub&gt;2&lt;/sub&gt;P–C&lt;sub&gt;6&lt;/sub&gt;F&lt;sub&gt;4&lt;/sub&gt;–B(C&lt;sub&gt;6&lt;/sub&gt;F&lt;sub&gt;5&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Catalysis; Reaction mechanism; Lewis acids and bases; Path (computing); Mechanism (biology); Base (topology)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001970315,0.0005723772,0.0002396595,0.0002190077,0.0002623291,0.00033729,0.0005130642,0.0004562122,0.01550058],"category_scores_gemma":[0.0002623791,0.0002285067,0.000290962,0.0001684281,0.0003606614,0.0007292382,0.0006197155,0.001114883,0.003222673],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005981082,"about_ca_system_score_gemma":0.0006527863,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007794062,"about_ca_topic_score_gemma":0.001208559,"domain_scores_codex":[0.9998215,0.00001397963,0.000005853511,0.00005449138,0.00003692526,0.00006733114],"domain_scores_gemma":[0.9998821,0.00001959711,0.0000212024,0.00003092572,0.00002113022,0.00002502908],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000262431,0.00008735943,0.0004512134,0.0002102161,0.00001922362,0.0002201194,0.0001058586,0.0003412388,0.9784763,0.009208789,0.001830735,0.008786442],"study_design_scores_gemma":[0.00001623829,0.0001777584,0.0003804516,0.000004101382,0.000006213064,0.0001125058,0.00003662948,0.0008185121,0.98882,0.0003828711,0.009234375,0.00001028951],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7991584,0.0013989,0.09504654,0.001424841,0.0008371501,0.0004505583,0.001698773,0.001621738,0.09836311],"genre_scores_gemma":[0.972356,0.0003873443,0.007782389,0.000182814,0.00004062445,0.00007690449,0.0005774986,0.0001591994,0.01843731],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01550058,"threshold_uncertainty_score":0.05185461,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01335727907609347,"score_gpt":0.2109414850915326,"score_spread":0.1975842060154391,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}