{"id":"W6884467958","doi":"10.1021/ja109192w.s002","title":"Stereo- and Regioselective Gold-Catalyzed Hydroamination of Internal Alkynes with Dialkylamines","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"","keywords":"Hydroamination; Alkyne; Regioselectivity; Amine gas treating; Stereoselectivity; Aryl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001741198,0.0003937079,0.0001279717,0.0001276486,0.0001127431,0.0001900132,0.0003866345,0.0002119438,0.001033558],"category_scores_gemma":[0.0001960598,0.000151199,0.0001860062,0.00009617979,0.0002104727,0.000321783,0.0003773151,0.0004320483,0.0006334698],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002668427,"about_ca_system_score_gemma":0.0001972638,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004869973,"about_ca_topic_score_gemma":0.001460236,"domain_scores_codex":[0.9998703,0.00001414341,0.00001477523,0.00003422019,0.00003208425,0.00003445922],"domain_scores_gemma":[0.9999284,0.00001075492,0.00001768547,0.00001816145,0.00001296016,0.00001208204],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003715965,0.00001781449,0.0001068695,0.00007381379,0.000007295825,0.0001651949,0.0000561836,0.0001715857,0.9929399,0.0007149466,0.00015119,0.00555793],"study_design_scores_gemma":[0.000004014619,0.00005932965,0.0001740926,0.000001646817,0.000003384726,0.000109592,0.000007660213,0.0002079244,0.9978581,0.00004200636,0.00152929,0.000002926628],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.960417,0.001085275,0.02301791,0.0001867327,0.00008972402,0.0000746964,0.0002734038,0.000312612,0.01454261],"genre_scores_gemma":[0.9876967,0.0005591601,0.007774479,0.0000303347,0.000009975294,0.00001661672,0.0001880548,0.00003905642,0.003685582],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001033558,"threshold_uncertainty_score":0.003457546,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01407352067644703,"score_gpt":0.2236859010689092,"score_spread":0.2096123803924622,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}