{"id":"W6884470533","doi":"10.1021/jo802629w.s002","title":"Conversion of Weinreb Amides into Benzene Rings Incorporating the Amide Carbonyl Carbon","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Advanced Synthetic Organic Chemistry","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Benzene; Amide; Aryl; Allylic rearrangement; Carbon fibers; Bromide; Carbon atom","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002008237,0.0004060088,0.0001395409,0.000174766,0.0001250306,0.0002103489,0.0002046807,0.000168519,0.002989514],"category_scores_gemma":[0.000174442,0.0001600176,0.0002319742,0.000207196,0.0001416001,0.0003724345,0.0002377753,0.0004252329,0.001639283],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000161127,"about_ca_system_score_gemma":0.000233752,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004609542,"about_ca_topic_score_gemma":0.001143743,"domain_scores_codex":[0.9999006,0.00001280717,0.000008147927,0.00001618083,0.00002148446,0.00004091657],"domain_scores_gemma":[0.9999274,0.000006908228,0.00002184224,0.00001514501,0.00001106803,0.00001766633],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008685877,0.00003958205,0.0001287756,0.00008789972,0.00001308282,0.0002413535,0.00005434228,0.0003885665,0.9889726,0.001715473,0.0001608948,0.008110562],"study_design_scores_gemma":[0.00001530321,0.0004375193,0.0007420207,0.000007449205,0.00001005495,0.0002279504,0.00002007652,0.0003067103,0.9893422,0.0001864114,0.00869554,0.000008706811],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9290425,0.003297247,0.03740644,0.0001865739,0.000184516,0.0001328405,0.001069576,0.0004510468,0.02822921],"genre_scores_gemma":[0.977103,0.002029899,0.01184005,0.00006065159,0.00001570552,0.00002889762,0.0005395755,0.00004837665,0.008333906],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002989514,"threshold_uncertainty_score":0.01000088,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0114622269606731,"score_gpt":0.2175934217275152,"score_spread":0.2061311947668421,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}