{"id":"W6884474904","doi":"10.1021/ja904185b.s001","title":"Hydrogen-Bonding Asymmetric Metal Catalysis with α-Amino Acids: A Simple and Tunable Approach to High Enantioinduction","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Catalysis; Simple (philosophy); Metal; Transition metal; Heterogeneous catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004913393,0.0008583696,0.0006170951,0.0004654488,0.0004621683,0.0008047616,0.001200752,0.0007967511,0.002620722],"category_scores_gemma":[0.0003831599,0.0004340035,0.0003542914,0.0004060769,0.0007839403,0.001287141,0.001170943,0.002039482,0.001908252],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005508185,"about_ca_system_score_gemma":0.0002639415,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002260927,"about_ca_topic_score_gemma":0.0003481205,"domain_scores_codex":[0.9996371,0.00004715479,0.00002957543,0.00007857667,0.0001406526,0.00006691433],"domain_scores_gemma":[0.9998498,0.00002939864,0.00002904887,0.00003702539,0.00002133394,0.00003338018],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000243998,0.0001658839,0.000230269,0.0004112411,0.00005398138,0.0006208539,0.000190988,0.0009011648,0.912089,0.04281839,0.003018293,0.03925598],"study_design_scores_gemma":[0.00006879722,0.0002470474,0.0001869393,0.00001447671,0.0000240506,0.0003619775,0.00003522458,0.00244726,0.9686767,0.004507405,0.02338577,0.00004436726],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6031979,0.01198228,0.2613753,0.003245163,0.001902882,0.0003791992,0.0007469981,0.002520106,0.1146502],"genre_scores_gemma":[0.9394434,0.004114568,0.04341121,0.0006421782,0.0002529428,0.0001221034,0.0002095563,0.0002531345,0.01155079],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002620722,"threshold_uncertainty_score":0.008767188,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01913118658987988,"score_gpt":0.2194660900784826,"score_spread":0.2003349034886027,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}