{"id":"W6884481451","doi":"10.1021/jo034334t.s001","title":"Stereoselective Synthesis of the Nonproteinogenic Amino Acid\\n(2<i>S</i>,3<i>R</i>)-3-Amino-2-hydroxydecanoic Acid from\\n(4<i>S</i>,5<i>S</i>)-4-Formyl-5-vinyl-2-oxazolidinone","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan; University of Regina","funders":"","keywords":"Stereoselectivity; Sulfone; Derivative (finance); Alcohol; Amino acid","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001236055,0.0004569702,0.0002429744,0.0001594941,0.0001773089,0.0001918274,0.0002753531,0.0002089155,0.001388486],"category_scores_gemma":[0.00007568749,0.0001298494,0.0001758498,0.0002358647,0.0001336519,0.0002164821,0.0002330341,0.0003883468,0.0009839779],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000395109,"about_ca_system_score_gemma":0.000737541,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00129731,"about_ca_topic_score_gemma":0.00215277,"domain_scores_codex":[0.9998928,0.000009169349,0.000008043958,0.00002971014,0.00002349613,0.00003685394],"domain_scores_gemma":[0.9999393,0.000003710433,0.00001825906,0.00001138071,0.00001097765,0.00001635705],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000533844,0.00001849159,0.00004294826,0.00005173859,0.0000036669,0.00006819854,0.0000213359,0.0001022075,0.9958961,0.0004642937,0.00009941271,0.003178212],"study_design_scores_gemma":[0.00000845704,0.0001263697,0.0003377016,0.000002536181,0.000004500359,0.00006857907,0.000009565725,0.0002269828,0.9952073,0.00004400296,0.003958264,0.00000578469],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9429235,0.002293465,0.03477586,0.0001376827,0.0002164082,0.0001420425,0.001445293,0.0005091978,0.01755654],"genre_scores_gemma":[0.9715404,0.001398644,0.01549047,0.00005056982,0.00001421437,0.00005752201,0.0009465944,0.00007744013,0.01042417],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001388486,"threshold_uncertainty_score":0.00464499,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01760985132993295,"score_gpt":0.218847624942979,"score_spread":0.2012377736130461,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}