{"id":"W6884485224","doi":"10.1021/jo201632c.s001","title":"Palladium-Catalyzed Selective\\nCarboelimination and\\nCross-Coupling Reactions of Benzocyclobutenols with Aryl Bromides","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Aryl; Cleavage (geology); Reaction mechanism; Yield (engineering); Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00008214532,0.0001677208,0.0001956167,0.00006984923,0.0001043143,0.00003457876,0.0001183768,0.000120869,0.04005627],"category_scores_gemma":[0.00112266,0.0001283253,0.00005365356,0.0002350878,0.00003239941,0.0002512499,0.00006197034,0.00009363088,0.00007276904],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000116661,"about_ca_system_score_gemma":0.0001070762,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002010007,"about_ca_topic_score_gemma":0.00001173007,"domain_scores_codex":[0.9989289,0.00000583899,0.0002840726,0.0003377087,0.0002558746,0.0001875815],"domain_scores_gemma":[0.9984058,0.0005377808,0.0002596644,0.0002986961,0.0004151067,0.00008290938],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001962041,0.0001035952,0.003667524,0.001033945,0.0002474856,0.000008770303,0.000179483,0.0002480071,0.9760473,0.0002641853,0.007983032,0.01002048],"study_design_scores_gemma":[0.001659211,0.00003734295,0.0221457,0.004180557,0.00008630996,0.00007889148,0.0001391113,0.001164815,0.9586442,0.0002871186,0.01112876,0.0004479976],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8008452,0.0007809251,0.002467567,0.0005785746,0.0001308131,0.0006214717,0.1825815,0.0006988833,0.01129505],"genre_scores_gemma":[0.9778444,0.00001589472,0.0009624346,0.00001208994,0.000133329,0.0001528997,0.01933013,0.00004729614,0.001501593],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1769991,"threshold_uncertainty_score":0.9608213,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03076597826660485,"score_gpt":0.2771067498688113,"score_spread":0.2463407716022065,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}