{"id":"W6884504475","doi":"10.1021/ol902216y.s001","title":"Asymmetric Addition of Alkenylstannanes to Alkylidene Meldrum’s Acids","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"","keywords":"Cationic polymerization; Enantioselective synthesis; Allylic rearrangement; Electrophile; Reagent","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002796793,0.000718599,0.0002628125,0.0002877627,0.0001957462,0.0003528508,0.0005609184,0.0003523381,0.002944374],"category_scores_gemma":[0.0002255395,0.0002570689,0.0003000709,0.0002224255,0.0002514384,0.0004989823,0.0006405177,0.0008017233,0.001682487],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003257817,"about_ca_system_score_gemma":0.0003308724,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003308794,"about_ca_topic_score_gemma":0.001136902,"domain_scores_codex":[0.9997439,0.00004770286,0.00002490605,0.00004275853,0.00005012063,0.00009061023],"domain_scores_gemma":[0.9999117,0.00001215603,0.00002096574,0.00002219083,0.00001106617,0.00002192504],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001322957,0.0000808739,0.0001721369,0.0002518584,0.00002800797,0.0008107765,0.0001815425,0.0005506736,0.9771485,0.006326552,0.0004425626,0.01387418],"study_design_scores_gemma":[0.00001218113,0.00007695015,0.0001382149,0.000003936769,0.0000079159,0.0002077054,0.00001452639,0.0003619297,0.9936594,0.00009877607,0.005412753,0.000005600343],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9217178,0.00314052,0.02849539,0.000421372,0.000374443,0.0001512728,0.0003056135,0.000341055,0.04505246],"genre_scores_gemma":[0.9774222,0.001879446,0.008576205,0.00008692393,0.00004437824,0.00003500291,0.0002084322,0.00005959866,0.01168781],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002944374,"threshold_uncertainty_score":0.009849906,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0252364661764468,"score_gpt":0.2710868165922631,"score_spread":0.2458503504158163,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}