{"id":"W6884508833","doi":"10.1021/ol902550q.s001","title":"Unprotected Vinyl Aziridines: Facile Synthesis and Cascade Transformations","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Cascade; Aziridine; Variety (cybernetics); Cascade reaction; Relay; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.00001869712,0.0001219532,0.0001229499,0.00003683124,0.0001236277,0.00003831424,0.0001163154,0.0001044248,0.3141417],"category_scores_gemma":[0.001010187,0.0000825064,0.00006790107,0.00007332511,0.00001047464,0.0001923975,0.00002174937,0.00006207745,0.001649576],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003874925,"about_ca_system_score_gemma":0.00003203511,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000009067775,"about_ca_topic_score_gemma":0.000007971519,"domain_scores_codex":[0.9993628,0.000006847689,0.0001570472,0.0001785,0.0001205813,0.000174174],"domain_scores_gemma":[0.9992054,0.0003722427,0.00004971555,0.0002367774,0.00004579869,0.00009007892],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002165223,0.0001106408,0.00007008449,0.0006914126,0.0001555791,0.00001453284,0.0004711399,0.000001697671,0.3900338,0.00006130391,0.2843085,0.3240597],"study_design_scores_gemma":[0.0001624475,0.000003533873,0.0005292373,0.001177304,0.00002202205,0.0000396615,0.0001446676,0.00003407701,0.5861948,0.00003753356,0.4114612,0.0001935401],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"dataset","genre_gemma":"empirical","genre_scores_codex":[0.0625885,0.0004921798,0.00004792799,0.002356863,0.0000445272,0.0003225359,0.8211135,0.0006622346,0.1123718],"genre_scores_gemma":[0.9936651,0.00002615463,0.00002358464,0.00002289607,0.00009276324,0.0006193912,0.003637223,0.00002201382,0.001890845],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.9310766,"threshold_uncertainty_score":0.9991277,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02540555592949193,"score_gpt":0.2253488659719327,"score_spread":0.1999433100424408,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}