{"id":"W6884512611","doi":"10.1021/ol100150f.s001","title":"Triquinanes: A “One-Pot” IMDA-Tandem Metathesis Cascade Strategy: Ring-Closing Metathesis (RCM) Dominates Norbornene ROM!","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Metathesis; Cascade; Intramolecular force; Norbornene; Tandem; Salt metathesis reaction; Acyclic diene metathesis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0004145729,0.0007265346,0.0009499948,0.0001015121,0.0002295017,0.0001770242,0.001029208,0.0005578321,0.4051463],"category_scores_gemma":[0.006983313,0.0005723331,0.0005131624,0.0003480754,0.00005963816,0.0003199168,0.0002981546,0.0003642602,0.001896682],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003903118,"about_ca_system_score_gemma":0.0002356975,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002043494,"about_ca_topic_score_gemma":0.000009569531,"domain_scores_codex":[0.9962534,0.0001503832,0.0008007422,0.00114074,0.0006673938,0.0009873006],"domain_scores_gemma":[0.9948135,0.002747968,0.0005044218,0.001328615,0.0002168617,0.0003886607],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005796413,0.0001798007,0.00004005584,0.0006827165,0.0004382922,0.0001272512,0.0002275563,0.000001753649,0.9273495,0.00001011588,0.008279616,0.06260534],"study_design_scores_gemma":[0.001118664,0.00002499445,0.0002611302,0.002911704,0.0003002741,0.0001308712,0.0002521347,0.00003812007,0.9596873,0.0003438489,0.03409921,0.000831769],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.583037,0.01299537,0.0001952735,0.002796672,0.0003582449,0.001328865,0.2643145,0.003561829,0.1314122],"genre_scores_gemma":[0.9844483,0.00007826662,0.003814345,0.00007790162,0.0007098959,0.0004116352,0.002488902,0.0002775486,0.007693278],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4032496,"threshold_uncertainty_score":0.9996728,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.06057439869692576,"score_gpt":0.284719242946146,"score_spread":0.2241448442492202,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}