{"id":"W6884513975","doi":"10.1021/ol0347794.s001","title":"(<i>Z</i>)-Tamoxifen and Tetrasubstituted\\nAlkenes and Dienes via a Regio- and\\nStereospecific Three-Component\\nMagnesium Carbometalation\\nPalladium(0) Cross-Coupling Strategy","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Propargyl; Grignard reagent; Reagent; Grignard reaction; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001622843,0.0003848794,0.000191634,0.0002352096,0.0001600572,0.0002075082,0.0005146183,0.0002457223,0.003087553],"category_scores_gemma":[0.00008180738,0.0002117912,0.0001983385,0.0002278774,0.0001827811,0.0002560828,0.0003656636,0.0004410663,0.001455293],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004194027,"about_ca_system_score_gemma":0.0003357526,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007671677,"about_ca_topic_score_gemma":0.001967921,"domain_scores_codex":[0.9999033,0.00001237872,0.000008340774,0.00002532992,0.0000247525,0.00002587586],"domain_scores_gemma":[0.9999641,0.000003418948,0.000008460583,0.000008072589,0.000006472728,0.000009534123],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007740482,0.00002749147,0.00007981236,0.00009341533,0.0000127903,0.000149373,0.00004262654,0.0002561286,0.9869536,0.002685024,0.0004411787,0.009181227],"study_design_scores_gemma":[0.00001544915,0.0001875475,0.0003385573,0.000005482371,0.00001296938,0.0003302368,0.00001113449,0.0003582961,0.9816041,0.0001477578,0.01697853,0.000009956247],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8633412,0.004721056,0.08751317,0.0005687253,0.0002201047,0.0004630323,0.001395953,0.00136723,0.04040942],"genre_scores_gemma":[0.9289632,0.002672241,0.04048467,0.0002277517,0.00002197296,0.0001873871,0.0009771321,0.0001300524,0.02633558],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003087553,"threshold_uncertainty_score":0.01032889,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02923455823943947,"score_gpt":0.255462868680306,"score_spread":0.2262283104408665,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}