{"id":"W6884515332","doi":"10.1021/om1011566.s001","title":"Comparison of Imine to Olefin Insertion Reactions: Generation of Five- and Six-Membered Lactams via a Nickel-Mediated CO, Olefin, CO, Imine Insertion Cascade","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Imine; Alkene; Olefin fiber; Migratory insertion; Steric effects; Cationic polymerization; Cascade","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003345722,0.0005289766,0.0003171442,0.0002124583,0.0001417566,0.0004353188,0.000521391,0.0004762112,0.001158159],"category_scores_gemma":[0.0003481345,0.0001891793,0.0002870508,0.0002154096,0.000240892,0.0004265093,0.0004472361,0.0005275714,0.0005861539],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003299473,"about_ca_system_score_gemma":0.0001900739,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003874587,"about_ca_topic_score_gemma":0.0008048782,"domain_scores_codex":[0.9997414,0.00004245129,0.00002661935,0.00005148047,0.00004673803,0.00009133277],"domain_scores_gemma":[0.9998357,0.00002723534,0.00004495421,0.00002398607,0.0000209224,0.00004715782],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003638203,0.0001108803,0.0002254944,0.0001414369,0.00002399312,0.0002247935,0.0001424729,0.0004326283,0.9926236,0.0005541099,0.00008769483,0.005069007],"study_design_scores_gemma":[0.00002666572,0.0007364635,0.0006381081,0.000005614649,0.00001764348,0.0001406519,0.00002481774,0.0008124453,0.9958416,0.00002746868,0.001716224,0.0000122074],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9910583,0.0008060805,0.003023961,0.00006128741,0.00002214338,0.00007214022,0.0001134407,0.00009872151,0.004743946],"genre_scores_gemma":[0.9945104,0.0004528779,0.002991973,0.00002640719,0.000003850799,0.00002952353,0.000113383,0.00001507023,0.001856622],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001158159,"threshold_uncertainty_score":0.003874362,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.06551452950429729,"score_gpt":0.3011114311156837,"score_spread":0.2355969016113864,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}