{"id":"W6903045093","doi":"10.1021/ol802185x.s001","title":"Aromatic &lt;i&gt;ortho&lt;/i&gt;-Benzylation Reveals an Unexpected Reductant","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Reduction (mathematics); Catalysis; Oxidation reduction; Redox; Benzyl alcohol","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0001629516,0.0002929708,0.0003007942,0.0001217008,0.000150321,0.00007889566,0.0003301218,0.0002458854,0.5043138],"category_scores_gemma":[0.004670617,0.0002459751,0.0001326169,0.0003842951,0.00002027297,0.0004076517,0.0001033967,0.0001084098,0.002591582],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002702916,"about_ca_system_score_gemma":0.0001620126,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000001611985,"about_ca_topic_score_gemma":0.00001205922,"domain_scores_codex":[0.9978141,0.0000871761,0.0005905383,0.0005893598,0.0005527407,0.000366047],"domain_scores_gemma":[0.997706,0.0004914055,0.0003703067,0.0009277886,0.0002646644,0.0002398636],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00002586272,0.00007648925,0.00004861714,0.0002132527,0.00004342151,0.00001169722,0.0001283549,0.00002309338,0.803555,0.0004074411,0.1895784,0.005888418],"study_design_scores_gemma":[0.002075871,0.00007686228,0.01025181,0.005075406,0.0001043822,0.0001555576,0.00006157792,0.002087703,0.1525386,0.003871187,0.8222644,0.001436681],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"dataset","genre_gemma":"empirical","genre_scores_codex":[0.2294097,0.003169206,0.002172113,0.001644945,0.001144766,0.001821805,0.5116463,0.004548762,0.2444423],"genre_scores_gemma":[0.6490812,0.00001640869,0.005035438,0.0002453183,0.001703206,0.0006932591,0.2963513,0.0002405157,0.04663328],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.6510164,"threshold_uncertainty_score":0.9999992,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04184858755016872,"score_gpt":0.2878524477258178,"score_spread":0.246003860175649,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}