{"id":"W6903071304","doi":"10.1021/jo901347u.s001","title":"Practical Synthesis and Highly Diastereoselective Diels−Alder Reactions of 1-Alkylthio-3-silyloxybutadienes","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Beetle Biology and Toxicology Studies","field":"Biochemistry, Genetics and Molecular Biology","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"","keywords":"Selectivity; Yield (engineering); Catalysis; Reaction conditions; Stereoselectivity","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005215831,0.0006251122,0.0003381617,0.0003670452,0.0002161049,0.0003341718,0.0003486834,0.0003989901,0.001909641],"category_scores_gemma":[0.0002065954,0.0003508407,0.0002837272,0.0002545425,0.0002546767,0.000418643,0.0003775846,0.0008169366,0.001040177],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003107583,"about_ca_system_score_gemma":0.0004539969,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002614853,"about_ca_topic_score_gemma":0.000933011,"domain_scores_codex":[0.9997608,0.00004635037,0.00001989789,0.00004425184,0.00006682937,0.00006179509],"domain_scores_gemma":[0.9999009,0.00001821203,0.00002404799,0.00001926579,0.00001623872,0.00002125256],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002619194,0.0000333095,0.0000633788,0.00009725522,0.000009443175,0.0001495211,0.00007003701,0.0004754101,0.992407,0.001420916,0.0001025438,0.005144981],"study_design_scores_gemma":[0.00001454268,0.0001444073,0.0002243721,0.000005318767,0.000008313308,0.0001823075,0.00001908626,0.0004584017,0.9939843,0.0002089136,0.004740271,0.000009672768],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8425611,0.008391405,0.1331904,0.0003819316,0.0001731481,0.0004712168,0.001243821,0.0005139248,0.01307302],"genre_scores_gemma":[0.9341673,0.005448325,0.05150202,0.00005824115,0.00002883033,0.0001628135,0.000833482,0.00007934284,0.007719719],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001909641,"threshold_uncertainty_score":0.006388366,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03731707446475448,"score_gpt":0.2913082745111817,"score_spread":0.2539912000464272,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}