{"id":"W6903090856","doi":"10.1021/ol200051m.s001","title":"Topochemical Polymerization of a Diarylbutadiyne Derivative in the Gel and Solid States","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Polydiacetylene-based materials and applications","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Polymerization; Thermochromism; Derivative (finance); Scanning electron microscope; Monomer; Diacetylene","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00001827543,0.00006029343,0.00007836001,0.00001128835,0.00002074793,0.00001109149,0.00009646959,0.00004134501,0.01821485],"category_scores_gemma":[0.0001559701,0.00003561375,0.00001450916,0.00004819083,0.00001419,0.00004323382,0.00003533099,0.00002642598,0.00002320257],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000007947467,"about_ca_system_score_gemma":0.00001776415,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001113446,"about_ca_topic_score_gemma":0.000002639144,"domain_scores_codex":[0.9996178,0.000009420697,0.0001160328,0.0001020762,0.00005874644,0.00009592351],"domain_scores_gemma":[0.9996184,0.0001501685,0.00005990003,0.0001310765,0.00001869273,0.00002178305],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000006581638,0.00002785865,0.000172354,0.00006840141,0.000003863812,6.590936e-7,0.0001892772,2.830875e-7,0.9948553,0.00007187392,0.00312841,0.001475135],"study_design_scores_gemma":[0.0002001854,0.000004837285,0.0006917956,0.0003440526,0.000002418571,0.000001776783,0.0000541102,0.00002031453,0.9952687,0.0003295732,0.003022334,0.00005990523],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8977726,0.000179202,0.000008394637,0.0005408886,0.000003683521,0.00007618984,0.1005019,0.00001922747,0.0008979535],"genre_scores_gemma":[0.9921285,0.00001820438,0.00001872693,0.00007148054,0.00003631656,0.0001560951,0.007513336,0.000006769151,0.00005056849],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0943559,"threshold_uncertainty_score":0.9826826,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01402750583116216,"score_gpt":0.2480585555407887,"score_spread":0.2340310497096265,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}